Title:
Golden cluster catalyst
Document Type and Number:
Japanese Patent JP6226341
Kind Code:
B2
Abstract:
PROBLEM TO BE SOLVED: To provide a gold cluster catalyst capable of promoting/controlling a chemical reaction with high catalytic activity and selectivity, and to provide a production method of the gold cluster catalyst.SOLUTION: The gold cluster catalyst is obtained by depositing a plurality of gold cluster compounds, each of which is stabilized by an organic ligand and has gold atoms of a predetermined atomic number, on a carrier and post-treating the gold cluster compound-deposited carrier, in other words, by depositing a cluster, which is obtained by assembling a plurality of gold atoms, on the carrier. The particle diameter of the cluster is 10 nm or smaller. The cluster almost consists of only the gold atoms. The number of the gold atoms is selected from 11, 55, and 101. The gold cluster catalyst is used as a hydrogenation catalyst of oxygen atom-containing organic compounds. The carrier of the gold cluster catalyst consists preferably of ceria or zirconia.SELECTED DRAWING: None
Inventors:
Haruta Masatake
Overhang
Huang Kaeru
Ayako Taketoshi
Ishida Tamao
Tomoki Akita
Atsushi Ogata
Golden summer
Overhang
Huang Kaeru
Ayako Taketoshi
Ishida Tamao
Tomoki Akita
Atsushi Ogata
Golden summer
Application Number:
JP2016056285A
Publication Date:
November 08, 2017
Filing Date:
March 18, 2016
Export Citation:
Assignee:
Tokyo Metropolitan University
National Institute of Advanced Industrial Science and Technology
National Institute of Advanced Industrial Science and Technology
International Classes:
B01J23/52; B01J23/63; C07C29/141; C07C33/32; C07C209/36; C07C211/46; C07C245/08
Domestic Patent References:
| JP2010247108A |
Other References:
佃達哉ほか,担持金クラスター触媒の精密合成とサイズ特異的酸化触媒活性,第105回触媒討論会討論会A予稿集,2010年 3月24日,第124頁
ZHU, Y. et al,Atomically Precise Au25(SR)18 Nanoparticles as Catalysts for the Selective Hydrogenation of α,β-Unsaturated Ketones and Aldehydes,Angewandte Chemie International Edition,2010年 1月14日,Vol.49, No.7,p.1295-1298,DOI:10.1002/anie.200906249
SHIMIZU, K. et al,Selective hydrogenation of nitrocyclohexane to cyclohexanone oxime by alumina-supported gold cluster catalysts,J. Mol. Catal. A Chem.,2011年 5月27日,Vol.345, No.1-2,p.54-59,DOI:10.1016/j.molcata.2011.05.018
FUJITANI, T. et al,Hydrogen Dissociation by Gold Clusters,Angewandte Chemie International Edition,2009年11月12日,Vol.48, No.50,p.9515-9518,DOI:10.1002/anie.200905380
ZHU, Y. et al,Atomically Precise Au25(SR)18 Nanoparticles as Catalysts for the Selective Hydrogenation of α,β-Unsaturated Ketones and Aldehydes,Angewandte Chemie International Edition,2010年 1月14日,Vol.49, No.7,p.1295-1298,DOI:10.1002/anie.200906249
SHIMIZU, K. et al,Selective hydrogenation of nitrocyclohexane to cyclohexanone oxime by alumina-supported gold cluster catalysts,J. Mol. Catal. A Chem.,2011年 5月27日,Vol.345, No.1-2,p.54-59,DOI:10.1016/j.molcata.2011.05.018
FUJITANI, T. et al,Hydrogen Dissociation by Gold Clusters,Angewandte Chemie International Edition,2009年11月12日,Vol.48, No.50,p.9515-9518,DOI:10.1002/anie.200905380
Attorney, Agent or Firm:
Yuichiro Matsuyama
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