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Title:
HERBICIDAL COMPOSITION BASED ON 2,6-DICHLORO-3-FLUORO-BENZONITRILE, AND NEW INTERMEDIATE
Document Type and Number:
Japanese Patent JPH08259510
Kind Code:
A
Abstract:

To obtain the subject composition useful as a selective herbicide by using a compound significantly simply obtained from easily available starting materials in a greatly high yield through the reaction of a specific toluene with chlorine and other additional reactions.

This herbicidal composition contains 2,6-dichloro-3- fluorobenzonitrile of formula I. The compound of formula I is preferably obtained by reacting 3-fluorotoluene of formula II with chlorine under conditions comprising a temperature of 0-100°C, etc., further reacting the obtained 2,6- dichloro-3-fluorotoluene with chlorine under conditions comprising 0-100°C, etc., reacting the obtained 2,6-dichloro-3-fluorobenzalchloride with water in the presence of a reaction auxiliary at 0-100°C, reacting the obtained 2,6-dichloro-3- fluorobenzaldehyde with hydroxylamine (acid adduct) at 0-100°C, and subsequently reacting the obtained 2,6-dichloro-3-fluoro-benzaldoxime of formula III with a dehydrating agent at 0-300°C under a pressure of 0.001-10 bar.


Inventors:
RAINHARUTO RANCHIYU
BERUNAA BUSUMAN
YOZEFU KESUBAUAA
MARUKUSU DORINGAA
HANSUUYOAHIMU ZANTERU
Application Number:
JP32251095A
Publication Date:
October 08, 1996
Filing Date:
November 17, 1995
Export Citation:
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Assignee:
BAYER AG
International Classes:
A01N37/34; C07C17/12; C07C17/14; C07C25/13; C07C45/43; C07C47/55; C07C63/04; C07C63/70; C07C231/02; C07C233/65; C07C249/08; C07C251/44; C07C251/48; C07C253/00; C07C253/20; C07C255/50; (IPC1-7): C07C255/50; A01N37/34; C07C25/13; C07C45/43; C07C47/55; C07C63/70; C07C231/02; C07C233/65; C07C249/08; C07C251/48; C07C253/00; C07C253/20
Attorney, Agent or Firm:
Heiyoshi Odashima