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Title:
へテロレプティック有機金属化合物
Document Type and Number:
Japanese Patent JP2010505002
Kind Code:
A
Abstract:
This invention relates to organometallic compounds represented by the formula (L1)xM(L2)y wherein M is a metal or metalloid, L1 and L2 are different and are each a hydrocarbon group or a heteroatom-containing group; x is a value of at least 1; y is a value of at least 1; x+y is equal to the oxidation state of M; and wherein (i) L1 has a steric bulk sufficiently large such that, due to steric hinderance, x cannot be a value equal to the oxidation state of M, (ii) L2 has a steric bulk sufficiently small such that, due to lack of steric hinderance, y can be a value equal to the oxidation state of M only in the event that x is not a value of at least 1, and (iii) L1 and L2 have a steric bulk sufficient to maintain a heteroleptic structure in which x+y is equal to the oxidation state of M; a process for producing the organometallic compounds, and a method for producing a film or coating from organometallic precursor compounds.

Inventors:
Mayale, Scott, Houston
Peck, John
Spong, Ronald, F.
Thompson, David, M.
Application Number:
JP2009530616A
Publication Date:
February 18, 2010
Filing Date:
September 28, 2007
Export Citation:
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Assignee:
Praxair Technology Incorporated
International Classes:
C07F7/10; C07F19/00; C23C16/40; C07F5/00; C07F7/00; C07F7/28; C07F9/00; C07F11/00; C07F17/00
Domestic Patent References:
JPH07502565A1995-03-16
JPS6216490A1987-01-24
JP2006182709A2006-07-13
JP2006013267A2006-01-12
JP2005132756A2005-05-26
JP2009541316A2009-11-26
Foreign References:
WO2005037847A12005-04-28
WO2005112101A22005-11-24
WO2007066546A12007-06-14
Other References:
JPN5009013672; YU,X. et al.: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY V126 N14, 2004, P4472-4473
JPN5009013673; CHEN,T. et al.: INORGANICA CHIMICA ACTA V345, 2003, P113-120
JPN5009013674; BUERGER,H. and NEESE, H. J.: INORGANIC AND NUCLEAR CHEMISTRY LETTERS V6 N3, 1970, P299-304
JPN6012032994; CAI, H. et al.: Canadian Journal of Chemistry Vol.81, No.11, 2003, p.1398-1405
JPN6012032996; CHANDRA,G. and LAPPERT M. F.: Journal of the Chemical Society [Section] A:  Inorganic, Physical, Theoretical No.8, 1968, p.1940-5
Attorney, Agent or Firm:
Asamura patent office
Hideto Asamura
Hajime Asamura
Katsunori Ando
Yuichiro Asano
Yoichiro Uemura