Title:
【発明の名称】脂肪族ジオールおよび環式エーテルを同時製造する方法
Document Type and Number:
Japanese Patent JP2003517028
Kind Code:
A
Abstract:
A process is described for the co-production of a diol product (e.g. butane-1,4-diol) and a cyclic ether (e.g. tetrahydrofuran) by hydrogenation of an aliphatic diester or lactone feedstock, such as dimethyl or diethyl maleate, which contains a minor amount of acidic material, such as the corresponding monoester. It utilises a plurality of hydrogenation zones (8, 9, 10) connected in series, each containing a charge (12, 17, 24) of a granular ester hydrogenation catalyst. The first hydrogenation zone (8) contains a bed (12) of a catalyst (e.g. reduced copper chromite) which is tolerant of a minor amount of acidic material, while the second hydrogenation zone (9) contains a bed (17) of a catalyst which provides enhanced yields of cyclic ethers compared to the catalyst of the first hydrogenation zone (8). A third hydrogenation zone (10) contains a bed (24) of a catalyst which exhibits low selectivity towards conversion of the diester to at least one byproduct (e.g. 2-(4'-hydroxybutoxy)-tetrahydrofuran). The feedstock is supplied to the first hydrogenation zone (8) as a vaporous stream comprising hydrogen and the hydrogenatable material and the zones (8, 9, 10) are typically operated under adiabatic conditions. From the third hydrogenation zone (10) there is recovered a final product stream which is substantially free of the hydrogenatable material and which contains the diol, cyclic ether and other byproducts, the selectivity to the cyclic ether being greater in the final product stream than in the first intermediate product stream.
Inventors:
Wood, Michael, Anthony
Willet, Paul
Wild, robert
Collie, stephan, william
Willet, Paul
Wild, robert
Collie, stephan, william
Application Number:
JP2001545238A
Publication Date:
May 20, 2003
Filing Date:
December 12, 2000
Export Citation:
Assignee:
Divy Process Technology Limited
International Classes:
C07B61/00; C07C29/149; C07C29/17; C07C31/20; C07D307/08; C07D307/20; C07D307/33; C07D315/00; (IPC1-7): C07D307/08; C07C29/149; C07C31/20; C07D307/33
Domestic Patent References:
| JPS62501702A | 1987-07-09 | |||
| JPS6122035A | 1986-01-30 | |||
| JPH04507417A | 1992-12-24 | |||
| JPS6399039A | 1988-04-30 | |||
| JPS5432409A | 1979-03-09 | |||
| JPS5395956A | 1978-08-22 | |||
| JPH07196549A | 1995-08-01 |
Foreign References:
| US4032458A | 1977-06-28 |
Attorney, Agent or Firm:
Nobuyuki Kaneda (2 others)