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Title:
IODONIUM COMPOUND USEFUL FOR PENTAFLUOROPHENYLATION AND PRODUCTION METHOD OF THE SAME, AND α-PENTAFLUOROPHENYL KETONE DERIVATIVE AND PRODUCTION METHOD OF THE SAME
Document Type and Number:
Japanese Patent JP2014221742
Kind Code:
A
Abstract:
PROBLEM TO BE SOLVED: To develop an iodonium compound useful for pentafluorophenylation and a production method of the same, and to develop a production method of an α-pentafluorophenyl ketone derivative using the developed iodonium compound.SOLUTION: An iodonium compound useful for pentafluorophenylation is developed by synthesizing the iodonium compound having a pentafluorophenyl group. In addition, by conducting direct pentafluorophenylation of β-ketoester using the developed iodonium compound as a key reaction, a synthesis of α-pentafluoro-β-ketoester is successful.

Inventors:
SHIBATA TETSUO
MATSUZAKI KOHEI
TOKUNAGA ETSUKO
Application Number:
JP2013101853A
Publication Date:
November 27, 2014
Filing Date:
May 14, 2013
Export Citation:
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Assignee:
NAGOYA INST TECHNOLOGY
International Classes:
C07C25/00; C07C17/266; C07C67/343; C07C69/757