Iron or the cobalt content Fischer Tropsch catalyst for higher hydrocarbon alternative composition

Japanese Patent JP5969001

B2

Cryptomelane-type manganese oxide octahedral molecular sieves (OMS-2) supported Fe and Co catalysts are utilized in a method for producing hydrocarbons by a Fischer-Tropsch mechanism. The hydrocarbon producing method includes providing a catalyst of a manganese oxide-based octahedral molecular sieve nanofibers with an active catalyst component of at least one of iron, cobalt, nickel, copper, manganese, vanadium, zinc, and mixtures thereof, and further containing an alkali metal. The formation of iron carbides and cobalt carbides by exposing the catalyst to conditions sufficient to form those carbides is also taught. After the catalyst has been appropriately treated, a carbon source and a hydrogen source are provided and contacted with the catalyst to thereby form a hydrocarbon containing product. The catalyst have high catalytic activity and selectivity (75%) for C2+ hydrocarbons in both CO hydrogenation and CO2 hydrogenation. Highly selective syntheses of high value jet fuel, C2-C6 alkenes, C2-C6 carboxylic acids; α-hydroxylic acids and their derivatives have been realized by tuning the oxidation ability of OMS-2 supports and by doping with Cu2+ ions.

Swives, Stephen, Elle.
Bo Shun, Who
Cradler, Eric, Roland
Brooks, Christopher, James

JP2014502653A

August 10, 2016

March 26, 2012

Click for automatic bibliography generation  

Honda motor industry stock company
UNIVERSITY OF CONNECTICUT

B01J29/03; C07C1/04; C07C1/12; C07C9/00; C07C11/00; C07C15/00; C07C45/00; C07C45/49; C07C47/00; C07C51/10; C07C53/08; C07C53/122; C07C59/01; C07D309/30

JP2007527783A
JP2010070548A

US8987160
WO1995025693A1

Isono Dozo

Previous Patent: The fuel cell of a high life provided with a proton exchange film

Next Patent: STRUCTURE SUCH AS FOLDABLE TABLE