To provide a laminate film with good blocking resistance and handling properties of the laminate film, a laminate printed article using it and a method for lamination in the laminate film with a heat-resistant base material, the first layer being a surface protective layer on the heat-resistant base material and the second layer being an adhesive layer provided on the first layer.

A transfer film layer of the laminate film in which the heat- resistant base material and the transfer film layer releasable on the heat- resistant base material are provided and the transfer film layer is transferred by heating and press-bonding on an image face of a printed article, comprises the first layer being the surface protective layer of the image face and the second layer provided on the first layer and being the adhesive layer on the image face, and as a resin ingredient constituting the second layer, a plurality of water-based emulsion resins with different glass transition temperatures are incorporated.