To provide a new leaving substituent-containing compound which is easily synthesized, has high solubility to an organic solvent, and can leave its substituent highly efficiently by application of external energy; an organic semiconductor material containing a compound highly efficiently obtained by adding external stimulation of heat or the like to the compound without forming a chemically unstable terminal olefin group; and an organic electronic device (especially an organic thin film transistor) using a film obtained by that the leaving substituent-containing compound is used as an organic semiconductor precursor and is made to form the film to be converted into an organic semiconductor by heat or the like.
The leaving substituent-containing compound includes a partial structure represented by formula (I). In the formula, at least one pair of (X1, X2) and (Y1, Y2) each denotes a hydrogen atom, and the other pair each denotes a group selected from the group consisting of a halogen atom and a substituted or unsubstituted 1C or more acyloxy group. In addition, a pair of the acyloxy groups of (X1, X2) or (Y1, Y2) may be identical or different, or may be bonded together to form a ring. R1 to R4 each denotes a hydrogen atom or a substituent. Q1, Q2 each denotes a hydrogen atom, a halogen atom or a monovalent organic group, and may be bonded together to form a ring.
YAMAMOTO SATOSHI
KOSAKA TOSHIYA
KATO TAKUJI
OKADA TAKASHI
SHINODA MASAHITO
MATSUMOTO SHINJI
MORI MASATAKA
YUTANI KEIICHIRO
| JPH0772664A | 1995-03-17 |
| WO2008026602A1 | 2008-03-06 | |||
| WO2008047896A1 | 2008-04-24 | |||
| WO2008050726A1 | 2008-05-02 |
JPN6014024839; ＬＥＯＮＡＲＤ Ｋ． ＤＹＡＬＬ ＡＮＤ ＪＯＨＮ Ａ． ＦＥＲＧＵＳＯＮ: 'Ｐｙｒｏｌｙｓｉｓ ｏｆ Ａｒｙｌ Ａｚｉｄｅｓ． ＸＩＩ． Ｍｅｃｈａｎｉｓｔｉｃ Ｉｍｐｌｉｃａｔｉｏｎｓ ｏｆ ｔｈｅ Ｖｅｒｙ Ｓｍａｌｌ Ｎｅｉｇｈｂｏｒｉｎｇ Ｇｒｏｕｐ Ｅｆｆｅｃｔｓ' ＡＵＳＴＲＡＬＩＡＮ ＪＯＵＲＮＡＬ ＯＦ ＣＨＥＭＩＳＴＲＹ ｖｏｌ．４７， ｎｏ．６, 1994, ｐａｇｅｓ １０３１-１０４２
JPN6014024846; ＳＨＩＮＪＩ ＹＡＭＡＤＡ ＡＮＤ ＨＩＲＯＫＯ ＫＡＴＳＵＭＡＴＡ: 'Ａｓｙｍｍｅｔｒｉｃ Ａｃｙｌａｔｉｏｎ ｏｆ ｓｅｃ-Ａｌｃｏｈｏｌｓ ｗｉｔｈ Ｔｗｉｓｔｅｄ Ａｍｉｄｅｓ Ｐｏｓｓｅｓｓｉｎｇ Ａｘｉａｌ Ｃｈｉｒａｌｉｔｙ Ｉｎｄｕｃｅｄ ｂｙ ｔｈｅ Ａ' ＪＯＵＲＮＡＬ ＯＦ ＯＲＧＡＮＩＣ ＣＨＥＭＩＳＴＲＹ ｖｏｌ．６４， ｎｏ．２４, 1999, ｐａｇｅｓ ９３６５-９３７３
JPN6014024849; ＷＩＮＧ-ＳＵＭ ＴＳＡＮＧ， ＥＴ ＡＬ．: 'Ｃｈｅｍｉｓｔｒｙ ｏｆ ａｎｔｉ- ａｎｄ ｓｙｎ-１，２：３，４-ｎａｐｈｔｈａｌｅｎｅ ｄｉｏｘｉｄｅｓ ａｎｄ ｔｈｅｉｒ ｐｏｔｅｎｔｉａｌ ｒｅｌｅｖａｎｃｅ ａｓ ｍｅｔａｂｏｌｉｃ ｉ' ＪＯＵＲＮＡＬ ＯＦ ＯＲＧＡＮＩＣ ＣＨＥＭＩＳＴＲＹ ｖｏｌ．４７， ｎｏ．２７, 1982, ｐａｇｅｓ ５３３９-５３５３
JPN6014024852; ＣＨＲＩＳＴＯＰＨＥＲ Ａ． ＲＯＳＡＲＩＯ， ＥＴ ＡＬ．: 'Ｓｙｎｔｈｅｓｉｓ ｏｆ ｐｏｔｅｎｔｉａｌ ｍｅｔａｂｏｌｉｔｅｓ ｏｆ ｄｉｂｅｎｚ［ａ，ｊ］ａｃｒｉｄｉｎｅ： ｄｉｈｙｄｒｏ ｄｉｏｌｓ ａｎｄ ｐｈｅｎｏｌｓ' ＪＯＵＲＮＡＬ ＯＦ ＯＲＧＡＮＩＣ ＣＨＥＭＩＳＴＲＹ ｖｏｌ．５２， ｎｏ．６, 1987, ｐａｇｅｓ １０６４-１０７２
JPN6014024854; ＲＯＬＡＮＤ ＫＯＳＴＥＲ， ＥＴ ＡＬ．: 'Ｒｅａｋｔｉｏｎｅｎ ｖｏｎ Ｎａｐｈｔｈａｌｉｎ， Ａｎｔｈｒａｃｅｎ ｕｎｄ Ｐｈｅｎａｎｔｈｒｅｎ ｍｉｔ Ｔｅｔｒａａｌｋｙｌｄｉｂｏｒａｎｅｎ （６）' ＣＨＥＭＩＳＣＨＥ ＢＥＲＩＣＨＴＥ． ｖｏｌ．１２２， ｎｏ．４, 1989, ｐａｇｅｓ ６７７-６８６
JPN6014024857; Ｈ． ＹＡＧＩ， ＥＴ ＡＬ．: 'Ｓｙｎｔｈｅｓｉｓ ａｎｄ ｒｅａｃｔｉｏｎｓ ｏｆ ｔｈｅ ｈｉｇｈｌｙ ｍｕｔａｇｅｎｉｃ ７，８-ｄｉｏｌ ９，１０-ｅｐｏｘｉｄｅｓ ｏｆ ｔｈｅ ｃａｒｃｉｎｏｇｅｎ ｂｅｎｚｏ［ａ］ｐｙ' ＪＯＵＲＮＡＬ ＯＦ ＴＨＥ ＡＭＥＲＩＣＡＮ ＣＨＥＭＩＣＡＬ ＳＯＣＩＥＴＹ ｖｏｌ．９９， ｎｏ．５, 1977, ｐａｇｅｓ １６０４-１６１１
JPN6014024861; Ｊ． Ｗ． ＣＯＯＫ， ＥＴ ＡＬ．: 'Ｏｘｉｄａｔｉｏｎ ｏｆ Ａｎｔｈｒａｃｅｎｅ ｂｙ Ｏｓｍｉｕｍ Ｔｅｔｒｏｘｉｄｅ' ＮＡＴＵＲＥ， ＩＮＴＥＲＮＡＴＩＯＮＡＬ ＷＥＥＫＬＹ ＪＯＵＲＮＡＬ ＯＦ ＳＣＩＥＮＣＥ ｖｏｌ．１６１， ｎｏ．４０８５, 1948, ｐａｇｅｓ ２３７-２３８
JPN6014024863; ＳＨＯＵＪＵＮ ＣＨＥＮ， ＥＴ ＡＬ．: 'Ａ Ｆａｃｉｌｅ Ｓｙｎｔｈｅｓｉｓ ｏｆ ９-Ｈｙｄｒｏｘｙｂｅｎｚｏ［ａ］Ｐｙｒｅｎｅ' ＯＲＧＡＮＩＣ ＰＲＥＰＡＲＡＴＩＯＮＳ ＡＮＤ ＰＲＯＣＥＤＵＲＥＳ ＩＮＴＥＲＮＡＴＩＯＮＡＬ ｖｏｌ．２９， ｎｏ．１, 1997, ｐａｇｅｓ １３１-１３４