Title:
1-ナフトール-ジ-又はトリ-スルフォン酸に基づく銅錯体アゾ染料を含むマゼンタインク
Document Type and Number:
Japanese Patent JP5116913
Kind Code:
B2
Abstract:
(a) Copper (Cu) complex azo dyes (IA) of 2-(2-hydroxy-1-phenylazo)-1-naphthol-3,8-disulfonic acids, (b) Cu complex azo dyes (IB) of 2-(2-hydroxy-1-phenylazo)-1-naphthol-3,6,8-trisulfonic acids and their salts (IC) with amines with a total of 11-14 carbon atoms are new. (a) Copper (Cu) complex azo dyes (IA) of formula (I); x = 0 of 2-(2-hydroxy-1-phenylazo)-1-naphthol-3,8-disulfonic acids and (b) Cu complex azo dyes (IB) of formula (I; x = 1 ) of 2-(2-hydroxy-1-phenylazo)-1-naphthol-3,6,8-trisulfonic acids and their salts (IC) of formula (I; x = 0 or 1 ) with amines of formula (II) with a total of 11-14 carbon (C) atoms are new;in (IA), X = hydroxy (OH), 1-4 carbon (C) (hydroxy)alkyl, vinyl, -CH2-CH2-Z or Z in (IA) and (IC) hydroxy (OH), 1-4 carbon (C) (hydroxy)alkyl, -CH2-CH2-Z or Z in (IB); Z = (substituted) 1-24 C alkoxy (optionally with oxygen (O) in the chain, a (substituted) phenoxy, 1-4 C alkylthio or phenylthio group, amino or N-mono- or N,N-di-(1-24 C alkyl)-amino, in which the alkyl group(s) may be substituted and/or have oxygen (-O-) or an imino group (-NR1-) in the chain; R1 = hydrogen (H), (substituted) 1-4 C alkyl, 10-20 C terpene-amino, (substituted) 5-7 C cycloalkylamino, (ring-substituted) phenyl, naphthyl, N-(1-4 C alkyl)-N-phenyl- or N-(1-4 C alkyl)-N-naphthylamino, morpholino, optionally N-substituted piperazin-1-yl or piperidiny-1-yl; R = 1-4 C alkyl, 1-4 C alkoxy or halogen; m, n = 0, 1 or 2; Ra, Rb, Rc = groups with a total of 11-14 C atoms with the exception of compounds (IA and IC; X = Z; Z = a group eliminated by alkali Independent claims are also included for (a) dye mixtures containing a dye of formula (I; x = 0 or 1 and dye(s) selected from specified xanthene and azo dyes; (b) inks containing a dye of formula (I), except (I; X = Z; Z = a group eliminated by alkali and an organic solvent; (c) the preparation of dyes (IA) and (IB);
Inventors:
Urs Lehmann
Marcel Flick
Marcel Flick
Application Number:
JP2000289908A
Publication Date:
January 09, 2013
Filing Date:
September 25, 2000
Export Citation:
Assignee:
Ciba Holding Inc.
International Classes:
B41M5/00; C09D11/00; C09B45/18; C09B62/515; C09B67/22; C09B67/26; C09B69/04; D06P1/10; D06P1/384; D06P5/00
Domestic Patent References:
JP57030773A | ||||
JP63030573A | ||||
JP55015505A |
Attorney, Agent or Firm:
Hajime Tsukuni
Yasuo Yanagibashi
Satoko Ito
Keiko Ozawa
Yasuhiro Oguni
Yoko Tanaka
Yoshinori Ikukawa
Akio Shibata
Fusayuki Saito
Yasuo Yanagibashi
Satoko Ito
Keiko Ozawa
Yasuhiro Oguni
Yoko Tanaka
Yoshinori Ikukawa
Akio Shibata
Fusayuki Saito