Title:
MANUFACTURE OF HIGH QUALITY AROMATIC AMINOAZO COMPOUND BY REARRANGEMENT OF 1*33DIARYLTRIAZENE
Document Type and Number:
Japanese Patent JPS5594349
Kind Code:
A
Abstract:
A 1,3-diaryl triazene, in a solution obtained by the diazotization-coupling of a primary aromatic monoamine with a gas containing NO and NO2, which solution contains the monoamine and up to about 30 percent by weight of the triazene, based on the weight of the solution, is contacted with 0.4-2.0 percent of a strong acid, preferably nitric acid (based on the weight of the triazene-containing solution), at 50 DEG -120 DEG C. The triazene rearranges to an aromatic amino azo compound in a high para/ortho isomer ratio with minimum formation of binuclear by-products.
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Inventors:
FURANKU EDOWAADO HAAKUSU
Application Number:
JP62680A
Publication Date:
July 17, 1980
Filing Date:
January 09, 1980
Export Citation:
Assignee:
DU PONT
International Classes:
C07C245/08; C07C67/00; C07C241/00; C07C245/24; C09B27/00; (IPC1-7): C07C107/06
Domestic Patent References:
| JPS53101316A | 1978-09-04 | |||
| JPS52142021A | 1977-11-26 |