PURPOSE: To obtain a polyester copolymer having a low melting point and a proper crystallinity by the copolymerization of a dicarboxylic acid or its ester- forming derivative, a low-molecular weight diol, and a high-molecular weight diol.
CONSTITUTION: A dicarboxylic acid or its ester-forming derivative (A) composed of terephthalic acid or a mixture of 50mol% or more terephthalic acid and one or more aromatic and aliphatic dicarboxylic acids other than terephthalic acid, a low-molecular weight diol (B) composed of a mixture of 1W50mol% 2-methyl- 1,3-propanediol and 99W50mol% 1,6-hexanediol, and one or more high-molecular weight diol (C) of polyalkylene ether glycols and polycaprolactone glycols (in such as amount that the proportion of the high-molecular weight diol component in the copolymer is 0W60wt%) are subjected to copolymerization.
OKAMOTO ICHIROU
JPS5225831A | 1977-02-26 | |||
JPS53102333A | 1978-09-06 | |||
JPS4917653A | 1974-02-16 | |||
JPS4834231A | 1973-05-17 | |||
JPS4832144A | 1973-04-27 |