MANUFACTURING METHOD OF CATALYST

Japanese Patent JP2018002803

A

PROBLEM TO BE SOLVED: To provide a manufacturing method of a catalyst capable of manufacturing a catalyst which is a metallocene compound by using a ligand with a specific structure containing a fluorene skeleton at high purity and high yield.SOLUTION: A catalyst is manufactured by a method including: a process (I) for reacting a ligand with a specific structure containing a fluorene skeleton and an organic lithium compound with a specific structure of 2.2 to 3.8 mol equivalent based on the ligand; a process (II) for reacting a Ti compound, a Zr compound or an Hf compound having a halogen atom or the like of 1 mol equivalent or more based on the ligand with a product of the process (I); a process (III) for reacting a product of the process (II) and an organic lithium compound with a specific structure so that total of the amount of the organic lithium compound used in the process (I) and the amount of the organic lithium compound used in the process (III) is 4 mol equivalent or more based on the ligand.SELECTED DRAWING: None

KIRAI NAOHIRO
OKANO YOSHIMICHI

JP2016129019A

January 11, 2018

June 29, 2016

Click for automatic bibliography generation  

POLYPLASTICS CO
DAICEL CORP

C08F4/6592; C07F19/00

JP2011174018A

2011-09-08

"Living polymerization of olefins with ansa-dimethylsilylene(fluorenyl)8amido)dimethyltitanium-based", POLYMER JOURNAL, vol. 43, JPN6020023529, 2011, pages 331 - 351, ISSN: 0004298007
"Stereospecific polymerization of propylene with group 4 ansa-fluorenylamidodimethyl complexes", JOUNAL OF ORGANOMETALLIC CHEMISTRY, vol. 691, JPN6020023530, 2006, pages 193 - 201, ISSN: 0004298008

Masayuki Masabayashi
Hayashi Ichiyoshi

Previous Patent: A polyamide imide resin composition and a paint

Next Patent: A manufacturing method of a catalyst