PURPOSE: To manufacture a metal - ceramic composite material of high releasability without generating cracks, peeling or the like because of the addition of the hot or cold cycle or the like.

CONSTITUTION: A polyborosiloxane resin coating material of superior heat resistance containing megnetic metallic powder such as Ni flake is applied on a non-magnetic metal material 1 such as a brass plate in a manner that the concentration of magnetic metallic powder is reduced gradually from the side of the nonmagnetic metal material 1 toward the surface and banked thereon. Then, an inorganic polymer coating material such as polyboro-siloxane resin is applied on the coat baked layer 2 to form a ceramic layer 3.