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Title:
METAL COMPLEX COMPRISING HETEROATOM AND TWO METALS
Document Type and Number:
Japanese Patent JP3822844
Kind Code:
B2
Abstract:

PROBLEM TO BE SOLVED: To provide a heterobimetallic transition metal complex utilizable as a homogeneous catalyst, etc.
SOLUTION: The metal complex represented by formula (1) (wherein, M1 denotes a tri-, a tetra- or a pentavalent transition metal; M2 denotes a transition metal; X denotes a hydrogen atom, a halogen atom, a 1-20C hydrocarbon group or an alkoxy group or an amino group: n is an integer of 1-3; R1 denotes a 1-20C hydrocarbon group or a hydrocarbon group having a silicon atom; R2 denotes a 1-20C hydrocarbon group; a hydrocarbon group having a silicon atom or an alkoxy group or an amino group; Z denotes an oxygen atom, a sulfur atom or an NR (wherein, R denotes an alkyl group) when Z is present; L denotes a halogen atom, a 1-20C hydrocarbon group or an akoxy group, a carbonyl group, phosphines, isonitriles, ethers or sulfides; and m denotes an integer of 2-4) or a dimer thereof is obtained. The metal complex is used as a catalyst for polymerizing olefins.


Inventors:
Hideo Nagashima
Koki Matsubara
Takashi Oda
Application Number:
JP2002168079A
Publication Date:
September 20, 2006
Filing Date:
June 10, 2002
Export Citation:
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Assignee:
Japan Science and Technology Agency
International Classes:
C07F7/28; C07F19/00; C07F9/50; C07F15/00; C07F15/04; C08F4/06; C08F10/00; B01J31/22; C07C45/50; (IPC1-7): C07F19/00; C08F4/06; C08F10/00; //C07F7/28; C07F9/50; C07F15/00; C07F15/04
Domestic Patent References:
JP2003261588A
Other References:
Organometallics,1991年,10(1),p.45-48
J.Am.Chem.Soc.,1994年,116(9),p.3822-3835
Angewandte Chemie International Edition,1999年,38(8),p.1086-1088
Journal of Organometallic Chemistry,2000年,604(1),p.116-125
J.Chem.Soc.,Dalton Trans.,2001年,18,p.2551-2553
Attorney, Agent or Firm:
Satoshi Tsutsui