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Title:
METAL COMPLEX USED IN METATHESIS
Document Type and Number:
Japanese Patent JP2010077128
Kind Code:
A
Abstract:

To provide a metal complex useful as a catalyst component in olefin metathesis reactions, atom or group transfer radical polymerization or addition reactions, and in vinylation reactions, and to provide use thereof.

There are provided pentacoordinate metal complexes of formulae (IC) and (ID) (wherein M is a transition metal (especially ruthenium) selected from the group consisting of groups 4, 5, 6, 7, 8, 9, 10, 11, and 12 in the periodic table; Z is selected from the group consisting of oxygen, sulfur, selenium, NR'''', PR'''', AsR'''', and SbR''''; R'', R''', and R'''' are each hydrogen, 1-6C alkyl, 3-8C cycloalkyl, 1-6C alkyl, or the like).


Inventors:
VERPOORT FRANCIS WALTER CORNELIUS
DE CLERCQ BOB
Application Number:
JP2009218735A
Publication Date:
April 08, 2010
Filing Date:
September 24, 2009
Export Citation:
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Assignee:
TELENE SAS
International Classes:
C07D321/00; C07F15/00; B01J31/28; C07B61/00; C07C4/10; C07C6/04; C07C11/107; C07C13/12; C07C13/20; C07C29/00; C07C35/06; C07C67/333; C07C69/74; C07C229/12; C07C251/24; C07F1/00; C07F1/08; C07F7/28; C07F9/00; C07F9/40; C07F9/572; C07F11/00; C07F13/00; C07F15/02; C07F15/04; C07F15/06; C07F19/00; C08F2/38; C08F4/00; C08F4/40; C08F4/72; C08G61/08
Domestic Patent References:
JP4477879B22010-06-09
Attorney, Agent or Firm:
Shigeaki Nishikawa
Naoto Noda
Yasuhide Nomura