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Title:
金属錯体、発光材料及び発光素子
Document Type and Number:
Japanese Patent JP5208391
Kind Code:
B2
Abstract:

To provide a new light emitting metal complex using as the central metal a metal M more abound in output and reserves than Ir and excellent in luminous efficiency, color purity and the like, and to provide a light emitting element using the complex.

The metal complex comprises a metal M selected from a group consisting of Sc, Ti, V, Cr, Mn, Fe, Cu, Zn, Y, Nb, Mo, Tc, Ru, Rh, Pd, Ag, Cd, Hf, Ta, W, Re, Pt, Au, Hg and the like and has no halogen unidentate ligand, wherein, at the highest occupied molecular orbit (HOMO) obtained by a computational scientific method, the rate of the sum of square of orbital coefficient of the outermost d orbital of M to the sum of squares of all atomic orbital coefficients is ≥ 1/3, the energy difference (S1-T1) between the lowest singlet excitation energy (S1) and the lowest triplet excitation energy (T1) is ≥0.1 (eV) but ≤1.0 (eV) and the oscillator strength (f) is ≥0.005 but ≤1.0.

COPYRIGHT: (C)2007,JPO&INPIT


Inventors:
Yoshihiko Akino
Chizu Sekine
Rei Okamura
Application Number:
JP2006244180A
Publication Date:
June 12, 2013
Filing Date:
September 08, 2006
Export Citation:
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Assignee:
Sumitomo Chemical Co., Ltd.
International Classes:
C07F15/00; C08K5/56; C08L65/00; C08L101/00; C08L101/02; C09D11/00; C09K11/06; H01L51/50
Domestic Patent References:
JP2003261568A
JP2004296170A
JP2006080419A
JP2006008996A
Other References:
Yuko Miyazaki, et al.,Preparation of new type of azacalixarene, azacalix[n](2,6)pyridine,Tetrahedron Letters,2002年10月28日,Vol.43, No.44,p.7945-7948
Attorney, Agent or Firm:
Hideto Asamura
Hajime Asamura
Yukihiro Ikeda
Naganuma Akio