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Title:
METAL MATERIAL FOR DECORATION
Document Type and Number:
Japanese Patent JP2013019038
Kind Code:
A
Abstract:

To provide a metal material for decoration, having a valve metal oxide film of which the discoloration over time is suppressed and which has high color retention.

The metal material for decoration has a surface layer which is formed by a high temperature heat treatment under low oxygen partial pressure of ≤100 Pa and composed of a valve metal oxide film. A layer directly below the surface layer is composed of a valve metal and a noble metal (excluding silver (Ag), the same applies hereinafter), and the noble metal is deposited and dispersed in the crystal grain boundary of the valve metal. In the range from the surface to a vertical depth of 30 μm, the crystal of the valve metal is a slender crystal grain in the vertical cross section from the surface, and in the range from the surface to a vertical depth of 30 μm, the content of the noble metal is 5 atom% or less.


Inventors:
OKAZAKI TAKESHI
Application Number:
JP2011155379A
Publication Date:
January 31, 2013
Filing Date:
July 14, 2011
Export Citation:
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Assignee:
TANAKA PRECIOUS METAL IND
International Classes:
C23C8/12; C22C14/00; C22C16/00; C22F1/18; C22F1/00
Domestic Patent References:
JPS5815534B21983-03-26
JPS5815534B21983-03-26
JP2003105561A2003-04-09
JP2008210773A2008-09-11
JP2010045038A2010-02-25
JPS4837332A1973-06-01
JP2007254856A2007-10-04
JP2009170116A2009-07-30
JP2009238438A2009-10-15
JP2010135232A2010-06-17
JP2009289511A2009-12-10