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Title:
METAL SILICATE OF TETRAVALENT LANTHANIDE AND ACTINIDE SERIESMETALS
Document Type and Number:
Japanese Patent JPS61122116
Kind Code:
A
Abstract:
A molecular sieving metallosilicate is disclosed which comprises a complex represented in terms of mole ratios of oxides by the formula:wherein A is an ammonium, alkyl ammonium, alkyl phosphonium or alkyl arsonium ion; D is an alkali or alkaline earth metal ion or a mixture of two or more thereof; E is selected from the group consisting of A1, B, Mo, W, Fe, or a mixture of two or more thereof; M is a tetravalent metal selected from the Lanthanide or Actinide series; a is a number ranging from zero to about 25; b is a number ranging from zero to about 1.5; c is a number ranging from zero to about 0.3; d is a number ranging from about 20 to about 500; e is a number ranging from zero to about 200. The X-ray diffraction pattern for these metallosilicates indicates a ZSM-5 like crystalline structure. A method for making these metallosilicates, and a method for dehydrating and reforming methanol using these metallosilicates are disclosed.

Inventors:
MAIKERU JIYOSEFU DESUMONDO
FUREDORITSUKU ANSONII PESA
JIENII KAMENNOFU SAARII
Application Number:
JP25645685A
Publication Date:
June 10, 1986
Filing Date:
November 15, 1985
Export Citation:
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Assignee:
STANDARD OIL CO OHIO
International Classes:
B01J29/00; B01J29/04; B01J29/40; C01B33/20; C01B39/10; C01B39/12; C01B39/40; C07B61/00; C07C1/00; C07C1/20; C07C11/02; C07C67/00; (IPC1-7): B01J29/04; C01B33/20; C07C1/20; C07C11/02
Attorney, Agent or Firm:
Minoru Nakamura