Title:
A Metala crown complex and a manufacturing method for the same
Document Type and Number:
Japanese Patent JP2016536335
Kind Code:
A
Abstract:
メタラクラウン錯体は、式：Ｌｎ（ＩＩＩ）［１２−ＭＣ−４］2［２４−ＭＣ−８］（式中、ＭＣは遷移金属（Ｍ（ＩＩ））及びヒドロキサム酸（ＨＡ）配位子からなる反復サブユニットを有するメタラクラウンマクロ環であり、該ヒドロキサム酸（ＨＡ）配位子はメタラクラウン錯体中に取り込まれたときに、配位子ベースの電荷移動状態を生じる）を有する。メタラクラウン錯体の製造方法の例において、メタラクラウン錯体中に取り込まれたときに、配位子ベースの電荷移動状態を生じるヒドロキサム酸（ＨＡ）配位子、遷移金属塩及び希土類塩を溶媒中に溶解し、溶液を形成する。溶液に塩基を添加する。溶液を所定の温度で所定の時間撹拌する。溶液に精製方法を受けさせ、メタラクラウン錯体の結晶を製造する。
Inventors:
Evan Earl. Tribedy
Vincent El. Pecoraro
Svetlana B. Uriciba
Stephane Putu
Joseph Jankorowitz
Alexandra Fauco-Colette
Ivana Maltanik
Vincent El. Pecoraro
Svetlana B. Uriciba
Stephane Putu
Joseph Jankorowitz
Alexandra Fauco-Colette
Ivana Maltanik
Application Number:
JP2016540427A
Publication Date:
November 24, 2016
Filing Date:
September 05, 2014
Export Citation:
Assignee:
The Regents of the University of Michigan
Ecole Polytechnique/Dgar
Ecole Polytechnique/Dgar
International Classes:
C07F19/00; C07D215/48; C07F3/06; C07F5/00; G02B1/02
Other References:
JANKOLOVITS ET AL.: "Using the Structural Versatility of Lanthanide Metallacrowns to Tune Anion Recognition, Self-Assembl", DESSERTATION, JPN7018002165, 2012, pages pp.156-158,163-164,168-169,177-178,
JANKOLOVITS ET AL.: "Assembly of Near-Infrared Luminescent Lanthanide Host(Host-Guest) Complexes With a Metallacrown Sand", ANGEW. CHEM. INT. ED., vol. 50, JPN6018023983, 2011, pages 9660 - 9664, XP055146970, DOI: doi:10.1002/anie.201103851
JANKOLOVITS ET AL.: "Isolation of Elusive Tetranuclear and Pentanuclear M(II)-Hydroximate Intermediates in the Assembly o", INORGANIC CHEMISTRY, vol. 52, JPN6018023985, 11 April 2013 (2013-04-11), pages 5063 - 5076, XP055438376, DOI: doi:10.1021/ic302831u
XIAO ET AL.: "Lanthanide Complex-Based Luminescent Probes for Highly Sensitive Time-Gated Luminescence Detection o", ANALYTICAL CHEMISTRY, vol. 84, JPN6018023986, 28 November 2012 (2012-11-28), pages 10785 - 10792
JANKOLOVITS ET AL.: "Assembly of Near-Infrared Luminescent Lanthanide Host(Host-Guest) Complexes With a Metallacrown Sand", ANGEW. CHEM. INT. ED., vol. 50, JPN6018023983, 2011, pages 9660 - 9664, XP055146970, DOI: doi:10.1002/anie.201103851
JANKOLOVITS ET AL.: "Isolation of Elusive Tetranuclear and Pentanuclear M(II)-Hydroximate Intermediates in the Assembly o", INORGANIC CHEMISTRY, vol. 52, JPN6018023985, 11 April 2013 (2013-04-11), pages 5063 - 5076, XP055438376, DOI: doi:10.1021/ic302831u
XIAO ET AL.: "Lanthanide Complex-Based Luminescent Probes for Highly Sensitive Time-Gated Luminescence Detection o", ANALYTICAL CHEMISTRY, vol. 84, JPN6018023986, 28 November 2012 (2012-11-28), pages 10785 - 10792
Attorney, Agent or Firm:
Atsushi Aoki
Takashi Ishida
Fukumoto product
Tetsuji Koga
Yoichi Watanabe
Ryotaro Takei
Takahide Sasaki
Takashi Ishida
Fukumoto product
Tetsuji Koga
Yoichi Watanabe
Ryotaro Takei
Takahide Sasaki
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