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Title:
METALLOCENE HAVING BENZO-FUSED INDENYL DERIVATIVE AS LIGAND, ITS PREPARATION AND ITS USE AS CATALYST
Document Type and Number:
Japanese Patent JPH06184179
Kind Code:
A
Abstract:

PURPOSE: To provide a new compd. having high stereoregularity, narrow range of mol.wt. and high mol.wt., and useful for a catalyst component of high mol.wt. polyolefine, etc.

CONSTITUTION: A new compd. of formula I [M1 is a metal of group IVb, Vb or VIb in the periodic table; R1 and R2 are each H, 1-10C alkyl, 1-10C alkoxy 6-10C aryl, or the like; R3 is H, halogen, (substd.) 1-10C alkyl or the like; R4-R10 are each R3 or the like; R11 is the group of formula II (R12 and R13 are each H, halogen, 1-10C alkyl, or the like; M2 is silicon, germanium or tin), etc.]. Dimethylsilanediyl bis(2-methyl-4,5-benzoindenyl)-zirconium dichloride is exemplified. Further, a compd. of formula I is obtained by reacting a compd. of formula III with a compd. of formula IV (X is halogen).


Inventors:
YURUGEN ROORUMAN
FUORUKAA DOORE
ANDOREASU UINTAA
FURANKU KIYUUBAA
Application Number:
JP31909992A
Publication Date:
July 05, 1994
Filing Date:
November 27, 1992
Export Citation:
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Assignee:
HOECHST AG
International Classes:
C07C49/675; C07F17/00; C08F4/42; C08F4/60; C08F4/602; C08F4/6192; C08F4/6592; C08F10/00; C08F110/06; C07F7/28; C07F7/30; C08F4/659; (IPC1-7): C07F17/00; C08F4/42; C08F10/00
Attorney, Agent or Firm:
Mitsufumi Ezaki (3 others)