Title:
トランス-1,4-ビス(アミノメチル)シクロヘキサンの製造方法
Document Type and Number:
Japanese Patent JP5562429
Kind Code:
B2
Abstract:
A method for producing trans-1,4-bis(aminomethyl)cyclohexane includes a nuclear hydrogenation step of producing a hydrogenated terephthalic acid or terephthalic acid derivative by nuclear hydrogenation of a terephthalic acid or terephthalic acid derivative, the terephthalic acid or terephthalic acid derivative being at least one selected from the group consisting of terephthalic acid, terephthalic acid ester, and terephthalic acid amide; a cyanation step of treating the hydrogenated terephthalic acid or terephthalic acid derivative with ammonia, thereby producing 1,4-dicyanocyclohexane, and producing trans-1,4-dicyanocyclohexane from the obtained 1,4-dicyanocyclohexane; and an aminomethylation step of treating the trays-1,4-dicyanocyclohexane with hydrogen, thereby producing trans-1,4-bis(aminomethyl)cyclohexane. Metal oxide is used as a catalyst in the cyanation step, and the obtained trans-1,4-dicyanocyclohexane has a metal content of 3000 ppm or less.
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Inventors:
Yoshimura Shigetoshi
Shinji Kiyono
Hama Tetsuya Ta
Eiji Watanabe
Saiko Sawada
Shinji Kiyono
Hama Tetsuya Ta
Eiji Watanabe
Saiko Sawada
Application Number:
JP2012537744A
Publication Date:
July 30, 2014
Filing Date:
October 05, 2011
Export Citation:
Assignee:
Mitsui Chemicals, Inc.
International Classes:
C07C209/48; B01J23/14; B01J23/44; B01J25/00; C07C209/84; C07C211/18; C07C253/22; C07C253/34; C07C255/46; C07B61/00
Domestic Patent References:
| JP2011006382A | 2011-01-13 | |||
| JP2001187765A | 2001-07-10 | |||
| JPS4121338B1 | ||||
| JPS6310752A | 1988-01-18 | |||
| JP2010163439A | 2010-07-29 | |||
| JP2001181223A | 2001-07-03 |
Foreign References:
| WO2012046781A1 | 2012-04-12 |
Attorney, Agent or Firm:
Hiroyuki Okamoto