To provide a method of manufacturing chemical manganese dioxide by selectively precipitating only Mn by use of oxidant from a sulfur reducing leaching solution, for selectively separating the Mn from a ternary system cathode active material (Li(Ni1/3Mn1/3Co1/3)O2) as a cathode active material of a lithium ion battery to be used for a mobile phone or an electric car.
The method of manufacturing chemical manganese dioxide from a ternary system cathode active material of the present invention includes: (a) a first leaching step of leaching ternary system cathode active material powder with a mixture of sulfur and a reducing agent; (b) a second leaching step of successively leaching the first leaching solution; and (c) a step of adding Na2S2O8 to the second leaching solution, and selectively precipitating Mn to manufacture chemical manganese dioxide.
KANG JIN-GU
SHU SEIKO
CHANG HAN-KWON
JPH1154159A | 1999-02-26 | |||
JPH03254065A | 1991-11-13 | |||
JPH08503918A | 1996-04-30 | |||
JP2007519210A | 2007-07-12 | |||
JPH1154159A | 1999-02-26 | |||
JPH03254065A | 1991-11-13 |
KR101011260B1 | 2011-01-26 | |||
KR101011260B1 | 2011-01-26 |