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Title:
METHOD OF MANUFACTURING CHEMICAL MANGANESE DIOXIDE FROM TERNARY SYSTEM CATHODE ACTIVE MATERIAL, CHEMICAL MANGANESE DIOXIDE MANUFACTURED BY THIS METHOD, AND SECONDARY BATTERY INCLUDING CHEMICAL MANGANESE DIOXIDE
Document Type and Number:
Japanese Patent JP2012204343
Kind Code:
A
Abstract:

To provide a method of manufacturing chemical manganese dioxide by selectively precipitating only Mn by use of oxidant from a sulfur reducing leaching solution, for selectively separating the Mn from a ternary system cathode active material (Li(Ni1/3Mn1/3Co1/3)O2) as a cathode active material of a lithium ion battery to be used for a mobile phone or an electric car.

The method of manufacturing chemical manganese dioxide from a ternary system cathode active material of the present invention includes: (a) a first leaching step of leaching ternary system cathode active material powder with a mixture of sulfur and a reducing agent; (b) a second leaching step of successively leaching the first leaching solution; and (c) a step of adding Na2S2O8 to the second leaching solution, and selectively precipitating Mn to manufacture chemical manganese dioxide.


Inventors:
SHIN NOBUAKI
KANG JIN-GU
SHU SEIKO
CHANG HAN-KWON
Application Number:
JP2012064061A
Publication Date:
October 22, 2012
Filing Date:
March 21, 2012
Export Citation:
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Assignee:
KOREA INST GEOSCIENCE & MINERA
International Classes:
H01M4/50; C01G45/02; H01M6/52; H01M10/54
Domestic Patent References:
JPH1154159A1999-02-26
JPH03254065A1991-11-13
JPH08503918A1996-04-30
JP2007519210A2007-07-12
JPH1154159A1999-02-26
JPH03254065A1991-11-13
Foreign References:
KR101011260B12011-01-26
KR101011260B12011-01-26
Attorney, Agent or Firm:
Sakaki Morishita