ガス吸着材料、その前駆体及びガス吸着材料の製造方法

Japanese Patent JP5759175

B2

A gas adsorption material has a three-dimensional structure in which a ligand (p-hydroxybenzoic acid) consisting essentially of an aromatic ring as a principal skeleton containing, a carboxyl group and a functional group capable of forming a coordinate bond, the functional group being other than the carboxyl group, and a metal nucleus (Zn) are bonded to each other at a ratio of 1 : 1 in a building unit. In the gas adsorption material, the ligand contains a hydroxyl group as the functional group other than the carboxyl group, and the carboxyl group and the functional group other than the carboxyl group are each bonded in at least one position to the metal nucleus, thereby constituting the three-dimensional structure. The gas adsorption material is produced by drying a precursor that is obtained by reacting the ligand and the metal nucleus with each other, dissolving the dried precursor in an organic solvent (acetone), heating and stirring a resultant solution to form a three-dimensional structure that includes the organic solvent as a crystal solvent, and removing the crystal solvent.

Furukawa Masahiro
Masashi Goto

JP2010530768A

August 05, 2015

June 26, 2009

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Nippon Insulator Co., Ltd.

B01J20/22; B01J20/30

JP2004161675A	2004-06-10
JP2005336129A	2005-12-08
JP2005255651A	2005-09-22
JP2000309592A	2000-11-07
JPS6169073A	1986-04-09
JP2004155766A	2004-06-03
JP2004161675A	2004-06-10

US20080177098A1

2008-07-24

JPN6014023493; Ｙａｎｇ　Ｑｕ，　ｅｔ　ａｌ: 'Ｓｙｎｔｈｅｓｉｓ　ａｎｄ　Ｃｒｙｓｔａｌ　Ｓｔｒｕｃｔｕｒｅ　ｏｆ　Ｃｏｐｐｅｒ　ＩＩ　ａｎｄ　Ｓｉｌｖｅｒ　Ｉ　Ｃｏｍｐｌｅｘ　ｗｉｔｈ　１，４-ｄｉａｚａｂｉｃｙｃｌｏ［２．２．２］ｏｃｔａｎｅ' Ｊｏｕｒｎａｌ　ｏｆ　Ｃｈｅｍｉｃａｌ　Ｃｒｙｓｔａｌｌｏｇｒａｐｈｙ Ｖｏｌ．３７，　Ｎｏ．８, 200708, ｐｐ．５７９-５８２

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