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Title:
METHOD FOR MANUFACTURING POLYPHENYLENESULFIDE RESIN
Document Type and Number:
Japanese Patent JP2007016142
Kind Code:
A
Abstract:

To obtain a polyphenylenesulfide resin that has a reduced volatile content and is industrially useful, from a polyphenylenesulfide oligomer of 800-20,000 of a weight average molecular weight.

A mixture containing at least a polyhalogenated aromatic compound, a sulfiding agent and an organic polar solvent is heated to polymerize into a polyphenylene sulfide resin, then cooled to 220°C or below to obtain slurry (A) containing at least a granular polyphenylene sulfide resin, a polyphenylene sulfide oligomer, the organic polar solvent, water and a halogenated alkali metal salt. The polyphenylene sulfide oligomer of 800-20,000 weight-average molecular weight is obtained by removing at least the granular polyphenylene sulfide resin, the organic polar solvent, water and the halogenated alkali metal salt from the slurry (A). The polyphenylene sulfide resin is produced by thermal oxidation of the polyphenylene sulfide oligomer at 150-260°C under gas phase oxidizing atmosphere.


Inventors:
HIGASHIHARA TAKESHI
ISHIO ATSUSHI
Application Number:
JP2005199600A
Publication Date:
January 25, 2007
Filing Date:
July 08, 2005
Export Citation:
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Assignee:
TORAY INDUSTRIES
International Classes:
C08G75/02; C08G75/0295
Domestic Patent References:
JPH11110034A1999-04-23
JPH06248078A1994-09-06
JPH0656994A1994-03-01
JPH0543692A1993-02-23
JPH08325454A1996-12-10
JPH03197562A1991-08-28
JPH06306170A1994-11-01
JP2002332351A2002-11-22
JP2007002172A2007-01-11
JPH11158280A1999-06-15