Title:
フェノール及びシクロヘキサノンの調製方法
Document Type and Number:
Japanese Patent JP2012532119
Kind Code:
A
Abstract:
Process for the preparation of phenol and cyclohexanone which comprises: a. the synthesis of cyclohexylbenzene by the hydro-alkylation of benzene by contact with hydrogen or the alkylation of benzene with cyclohexene using Y zeolites; b. the selective aerobic oxidation of cyclohexylbenzene to the corresponding hydroperoxide catalyzed by N-hydroxy-derivatives in the presence of polar solvents; and c. the scission of the hydroperoxide of cyclohexylbenzene to phenol and cyclohexanone by homogeneous or heterogeneous acid catalysts; characterized in that the synthesis of cyclohexylbenzene takes place in the presence of a catalytic system comprising a Y zeolite and an inorganic ligand wherein the Y zeolite has a crystalline structure with openings consisting of 12 tetrahedra and the inorganic ligand is gamma-alumina, and wherein said catalytic composition is characterized by a pore volume, obtained by adding the mesoporosity and macroporosity fractions, greater than or equal to 0.7 cm3/g, wherein at least 30% of said volume consists of pores with a diameter greater than 100 nanometers.
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| JPS6185397 | SEPARATION OF SACCHARIDES |
Inventors:
Benigno Elena
Gambalotti Christian
Melone Lucio
Pastry nadia
Prosperini Simona
Punta Carlo
Lecpero Francesco
Gambalotti Christian
Melone Lucio
Pastry nadia
Prosperini Simona
Punta Carlo
Lecpero Francesco
Application Number:
JP2012518136A
Publication Date:
December 13, 2012
Filing Date:
June 23, 2010
Export Citation:
Assignee:
POLIMERI EUROPA S.P.A.
International Classes:
C07C27/00; C07C37/08; C07C39/04; C07C45/53; C07C49/403; C07B61/00
Domestic Patent References:
| JP2010535822A | 2010-11-25 | |||
| JP2010536862A | 2010-12-02 | |||
| JP2006510479A | 2006-03-30 | |||
| JP2007099745A | 2007-04-19 |
Attorney, Agent or Firm:
Koichi Tsujii
Sadao Kumakura
Atsushi Hakoda
Kenji Asai
Kazuo Yamazaki
Satsuki Ichikawa
Sadao Kumakura
Atsushi Hakoda
Kenji Asai
Kazuo Yamazaki
Satsuki Ichikawa