To provide a method for producing 2,3-pyridinedicarboxylic acid, suitable for industrialization by which a high purity product is produced in high yield by effectively utilizing a waste liquid.
The method for producing the 2,3-pyridinedicarboxylic acid comprises (a) a step for oxidizing quinoline or 8-hydroxyquinoline in water in the presence of a copper ion, and crystallizing and separating a copper salt of the 2,3-pyridinedicarboxylic acid, (b) a step for reacting an alkali with the separated copper salt of the 2,3-pyridinedicarboxylic acid in water to provide an aqueous solution of the alkali salt thereof, and (c) a step for crystallizing and separating the 2,3-pyridinedicarboxylic acid by reacting a mineral acid with the obtained aqueous solution of the alkali metal salt of the 2,3-pyridinedicarboxylic acid. (A) The whole or a part of the aqueous solution obtained after separating the 2,3-pyridinedicarboxylic acid at the step (c) is used at least as a part of the water used in the steps (a) or (b), or (B) copper or a copper compound is added to the whole or a part of the aqueous solution to recover the 2,3-pyridinedicarboxylic acid in the aqueous solution as the copper salt, and the resultant aqueous solution is recycled to and used in the step (b).
NAMEKATA TAKESHI
HEBEI SINOCHEM FUHENG CO LTD