Title:
Method for producing 5-hydroxymethyl-2-furfural
Document Type and Number:
Japanese Patent JP6293333
Kind Code:
B2
Abstract:
An object of the present invention is to provide a method for producing 5-hydroxymethyl-2-furfural (5-HMF) suitable for industrial-scale production and a novel catalyst composition for use in synthesizing 5-HMF. The present invention provides a method for producing 5-HMF comprising performing a dehydration reaction of a carbohydrate comprising a hexose as a constituent sugar or a derivative thereof by using activated carbon as a catalyst; and a catalyst composition for use in the reaction for producing 5-HMF from a carbohydrate comprising a hexose as a constituent sugar through a dehydration reaction, the catalyst composition comprising activated carbon.
Inventors:
Yuichi Nishimura
Tokuju Hamaguchi
Takaguchi
Tokuju Hamaguchi
Takaguchi
Application Number:
JP2017082634A
Publication Date:
March 14, 2018
Filing Date:
April 19, 2017
Export Citation:
Assignee:
Nippon Food Kako Co., Ltd.
International Classes:
C07D307/46; A23L33/10; A61K31/341; A61P7/06; B01J27/138; B01J27/16; C07D307/68; C08G63/58
Domestic Patent References:
| JP10265468A | ||||
| JP2008207995A | ||||
| JP2011176043A | ||||
| JP2010168238A | ||||
| JP2008088134A | ||||
| JP2009001519A | ||||
| JP2015506389A | ||||
| JP2008193933A | ||||
| JP2011136859A |
Foreign References:
| US20140371473 | ||||
| WO2014180979A1 | ||||
| WO2010077133A1 |
Other References:
KILIC, Emre et al.,Fructose Dehydration to 5-Hydroxymethylfurfural over Sulfated TiO2-SiO2, Ti-SBA-15, ZrO2, SiO2, and,Industrial & Engineering Chemistry Research,2015年,Vol.54, No.19,p.5220-5,DOI 10.1021/acs.iecr.5b00628
WANG, Jianjian et al.,Efficient catalytic conversion of fructose into hydroxymethylfurfural by a novel carbon-based solid,Green Chemistry,2011年,Vol.13, No.10,p.2678-81,ISSN:1463-9262
YANG, Li et al.,Dehydration of fructose into 5-hydroxymethylfurfural catalyzed by phosphorylated activated carbon ca,Asian Journal of Chemistry,2015年,Vol.27, No.8,p.2979-82,DOI 10.14233/ajchem.2015.18344
QI, Xinhua et al.,Acid-Catalyzed Dehydration of Fructose into 5-Hydroxymethylfurfural by Cellulose-Derived Amorphous C,ChemSusChem,2012年,Vol.5, No.11,p.2215-20,ISSN:1864-5631
LIU, Ruliang et al.,Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid,Green Chemistry,2013年,Vol.15, No.10,p.2895-903,ISSN:1463-9262
RUSSO, P. A. et al.,Solid acids with SO3H groups and tunable surface properties: versatile catalysts for biomass convers,Journal of Materials Chemistry A,2014年,Vol.2, No.30,p.11813-24,ISSN:2050-7496
FABICOVICOVA, Katarina et al.,Hydrogenolysis of cellulose to valuable chemicals over activated carbon supported mono- and bimetall,Green Chemistry,2014年,Vol.16, No.7,p.3580-8,DOI 10.1039/C4GC00664J
化学便覧 応用化学編,2003年,第6版,p.664, 722
SAIRANEN, Emma et al.,Functionalized Activated Carbon Catalysts in Xylose Dehydration,Topics in Catalysis,2013年,Vol.56, No.9-10,p.512-21,DOI 10.1007/s11244-013-0013-6
活性炭-基礎と応用,1981年,第4刷,p.79-85,264-269
WANG, Jianjian et al.,Efficient catalytic conversion of fructose into hydroxymethylfurfural by a novel carbon-based solid,Green Chemistry,2011年,Vol.13, No.10,p.2678-81,ISSN:1463-9262
YANG, Li et al.,Dehydration of fructose into 5-hydroxymethylfurfural catalyzed by phosphorylated activated carbon ca,Asian Journal of Chemistry,2015年,Vol.27, No.8,p.2979-82,DOI 10.14233/ajchem.2015.18344
QI, Xinhua et al.,Acid-Catalyzed Dehydration of Fructose into 5-Hydroxymethylfurfural by Cellulose-Derived Amorphous C,ChemSusChem,2012年,Vol.5, No.11,p.2215-20,ISSN:1864-5631
LIU, Ruliang et al.,Conversion of fructose into 5-hydroxymethylfurfural and alkyl levulinates catalyzed by sulfonic acid,Green Chemistry,2013年,Vol.15, No.10,p.2895-903,ISSN:1463-9262
RUSSO, P. A. et al.,Solid acids with SO3H groups and tunable surface properties: versatile catalysts for biomass convers,Journal of Materials Chemistry A,2014年,Vol.2, No.30,p.11813-24,ISSN:2050-7496
FABICOVICOVA, Katarina et al.,Hydrogenolysis of cellulose to valuable chemicals over activated carbon supported mono- and bimetall,Green Chemistry,2014年,Vol.16, No.7,p.3580-8,DOI 10.1039/C4GC00664J
化学便覧 応用化学編,2003年,第6版,p.664, 722
SAIRANEN, Emma et al.,Functionalized Activated Carbon Catalysts in Xylose Dehydration,Topics in Catalysis,2013年,Vol.56, No.9-10,p.512-21,DOI 10.1007/s11244-013-0013-6
活性炭-基礎と応用,1981年,第4刷,p.79-85,264-269
Attorney, Agent or Firm:
Noritaka Yokota
Enoki Yasutaka
Omori Miko
Enoki Yasutaka
Omori Miko