To provide a method for producing an aqueous resin dispersion excellent in stability, even upon a large scale production, without viscosity increase in an emulsion and generation of a large amount of aggregates etc. when producing a polymer having a large amount of carboxyl groups useful for an alkali-soluble thickener etc. by emulsion polymerization.
A preemulsion is prepared by adding a liquid monomer mixture prepared in advance in an another container to an emulsifier aqueous solution and stirring the resulting material, and emulsion polymerization is carried out. Preferably, a preemulsion-preparing process and/or an emulsifier aqueous solution-preparing process is carried out within a temperature range of polymerization starting temperature±20°C.
JPS61171775A | 1986-08-02 | |||
JPH11293081A | 1999-10-26 | |||
JPS6490206A | 1989-04-06 | |||
JP2002521507A | 2002-07-16 | |||
JPS6143607A | 1986-03-03 | |||
JP2008069249A | 2008-03-27 | |||
JP2003246909A | 2003-09-05 | |||
JPH0578434A | 1993-03-30 |
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