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Title:
METHOD FOR PRODUCING COMPOUND CONTAINING DICHLOROMETHYL GROUP
Document Type and Number:
Japanese Patent JP2012111717
Kind Code:
A
Abstract:

To provide a method for obtaining a compound containing a dichloromethyl group from a compound containing a trichloromethyl group, capable of efficiently eliminating chlorine by cutting one carbon-chlorine bond in the trichloromethyl group at a high selectivity under a gentle condition, and capable of easily separating a catalyst from a product after the reaction to be reused.

The method for obtaining the compound containing the dichloromethyl group includes elimination of chlorine by cutting one carbon-chlorine bond in the trichloromethyl group by wetly contacting the compound containing the trichloromethyl group with a precious metal catalyst under a hydrogen atmosphere. The precious metal catalyst is preferably a catalyst containing carbon particles and at least one kind of precious metal supported by the carbon particles and selected from a group including platinum, palladium and rhodium.


Inventors:
SAJIKI HIRONAO
KADOGUCHI HIROYA
Application Number:
JP2010262249A
Publication Date:
June 14, 2012
Filing Date:
November 25, 2010
Export Citation:
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Assignee:
NE CHEMCAT CORP
International Classes:
C07B35/06; B01J23/42; B01J23/44; B01J23/46; C07C17/23; C07C22/04; C07C29/58; C07C33/46; C07C41/24; C07C43/225; C07C67/317; C07C69/63; C07C231/12; C07C233/07; C07C269/06; C07C271/26; C07D207/333; C07D209/12; C07D213/61; C07B61/00
Domestic Patent References:
JPS4120215B1
JPH05320132A1993-12-03
JPH08510737A1996-11-12
JP2008545667A2008-12-18
JPH06298680A1994-10-25
JPH05320076A1993-12-03
JPH07285890A1995-10-31
JPH09194401A1997-07-29
JP2001019646A2001-01-23
JP2004099590A2004-04-02
JP2009185025A2009-08-20
Foreign References:
US3917612A1975-11-04
Other References:
JPN6014016505; Tetrahedron Letters 41, 2000, p.9357-9360
JPN6014016507; Tetrahedron 62, 2006, p.8384-8392
JPN6014016510; Journal of the American Chemical Society 76, 1954, p.4486
Attorney, Agent or Firm:
Shuji Iwamiya