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Title:
環化化合物の製造方法
Document Type and Number:
Japanese Patent JP4324670
Kind Code:
B2
Abstract:

To provide an eco-friendly method for quickly producing a cyclic compound without generating waste materials by using a supercritical, subcritical or pressurized carbon dioxide as a substitute solvent for conventional organic solvent in the Robinson reaction to synthesize a cyclic compound from ketones and vinylketones.

The method for the production of the cyclic compound comprises the synthesis of the cyclic compound by the cyclization reaction or ring condensing reaction of ketones and vinylketones in one step in the presence of a supercritical, subcritical or pressurized carbon dioxide. The invention provides a synthetic method capable of efficiently carrying out a complicate Robinson reaction in a short time compared with conventional methods. The objective compound is synthesized by a near zero-emission process in high selectivity and yield.

COPYRIGHT: (C)2005,JPO&NCIPI


Inventors:
Hajime Kawanami
Yutaka Ikushima
Application Number:
JP2004017633A
Publication Date:
September 02, 2009
Filing Date:
January 26, 2004
Export Citation:
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Assignee:
National Institute of Advanced Industrial Science and Technology
International Classes:
C07C45/64; C07C45/72; C07C45/66; C07C49/403; C07C49/497; C07C49/513; C07C49/603; C07C49/623; C07C49/633; C07C49/637; C07C49/643; C07C49/657; C07C49/665; C07C49/67; C07C49/675; C07C49/733; C07C49/737
Domestic Patent References:
JP2001131111A
JP2003096020A
JP11049722A
JP2003238473A
JP3081242A
JP2002284729A
JP2004210705A
JP2005206549A
Attorney, Agent or Firm:
Masahiko Sudo