Title:
二酸化炭素の共存下のフィッシャートロプシュ法による炭化水素類の製造方法
Document Type and Number:
Japanese Patent JP4660039
Kind Code:
B2
Abstract:
PROBLEM TO BE SOLVED: To provide a method for producing a hydrocarbon from a synthesis gas, wherein the reaction can stably and smoothly be carried out in the coexistence of carbon dioxide in high chain-growing probability, excellent olefin selectivity, excellent C5 + productivity, and high catalyst activity. SOLUTION: This method for producing the hydrocarbon comprises preliminarily reducing a catalyst which is prepared by carrying a constant amount of the compound of at least one metal selected from alkali metals, alkaline earth metals rare earth metals and the group III elements in the periodic table and a constant amount of ruthenium on a carrier comprising an aluminum oxide and a manganese oxide in which the average number of charges of manganese exceeds Mn<2+> , dispersing the pre-reduced catalyst in a liquid hydrocarbon in a constant concentration, and then bringing the synthesis gas into contact with the catalyst in the coexistence of a constant amount of carbon dioxide at a constant pressure and at a constant reaction temperature.
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Inventors:
Osamu Iwamoto
Shigenori Nakashizuka
Kinjiro Saito
Takashi Suzuki
Shigenori Nakashizuka
Kinjiro Saito
Takashi Suzuki
Application Number:
JP2001300819A
Publication Date:
March 30, 2011
Filing Date:
September 28, 2001
Export Citation:
Assignee:
Incorporated Administrative Agency Petroleum Natural Gas/Metallic Mineral Resources Organization
Cosmo Oil Co., Ltd.
Cosmo Oil Co., Ltd.
International Classes:
B01J23/34; B01J23/656; C10G2/00; B01J32/00; B01J35/10; B01J37/02; B01J37/18; C07B61/00; C07C1/04; C07C9/08; C07C9/15; C07C11/06
Domestic Patent References:
| JP11179204A | ||||
| JP59048424A | ||||
| JP4205301B2 | ||||
| JP4118503B2 |
Foreign References:
| US4728672 | ||||
| US5348982 | ||||
| US6121333 | ||||
| US4585799 | ||||
| EP0253924A1 | ||||
| EP0533227A1 |
Other References:
日本化学会第80秋季年会,2001年 3月,p.197
Attorney, Agent or Firm:
Shohei Oguri
Hironori Honda
Toshimitsu Ichikawa
Takeshi Takamatsu
Hironori Honda
Toshimitsu Ichikawa
Takeshi Takamatsu