Title:
単環芳香族炭化水素の製造方法
Document Type and Number:
Japanese Patent JP4961052
Kind Code:
B2
Abstract:
A method for producing monocyclic aromatic hydrocarbons of 6 to 8 carbon number from a feedstock oil containing polycyclic aromatic hydrocarbons and saturated hydrocarbons and having a 10 volume % distillation temperature of at least 140°C and a 90 volume % distillation temperature of not more than 380°C, the method comprising a cracking and reforming reaction step of bringing the feedstock oil into contact with a monocyclic aromatic hydrocarbon production catalyst comprising a crystalline aluminosilicate to cyclize and dehydrogenate the saturated hydrocarbons and to partially hydrogenate the polycyclic aromatic hydrocarbons using a hydrogen transfer reaction from the saturated hydrocarbons, thereby obtaining a product comprising monocyclic aromatic hydrocarbons of 6 to 8 carbon number, a hydrogenation reaction step of hydrogenating a portion of the product obtained in the cracking and reforming reaction step, a refining and collection step of refining and collecting monocyclic aromatic hydrocarbons of 6 to 8 carbon number by distilling a hydrogenation reaction product obtained in the hydrogenation reaction step, a recycling step of returning a heavy fraction of 9 or more carbon number, which has been separated and removed from the monocyclic aromatic hydrocarbons of 6 to 8 carbon number in the refining and collection step, to the cracking and reforming reaction step, a hydrogen recovery step of recovering, from the product obtained in the cracking and reforming reaction step, hydrogen that is produced as a byproduct in the cracking and reforming reaction step, and a hydrogen supply step of supplying the hydrogen recovered in the hydrogen recovery step to the hydrogenation reaction step, wherein the monocyclic aromatic hydrocarbon production catalyst includes at least one of phosphorus, boron, gallium, and zinc, and supply of hydrogen from an external source is completely eliminated.
Inventors:
Shinichiro Yanagawa
Masahide Kobayashi
Masahide Kobayashi
Application Number:
JP2011514211A
Publication Date:
June 27, 2012
Filing Date:
March 25, 2011
Export Citation:
Assignee:
jx Nikko Nisseki Energy Co., Ltd.
International Classes:
C10G65/12; B01J29/40; C07C4/18; C07C6/06; C07C15/02; C10G35/095; C10G47/20; C07B61/00
Domestic Patent References:
| JP2009235248A | 2009-10-15 | |||
| JPH032128A | 1991-01-08 | |||
| JPH0352993A | 1991-03-07 | |||
| JPH0326791A | 1991-02-05 | |||
| JPH03177496A | 1991-08-01 | |||
| JPS53116328A | 1978-10-11 | |||
| JPS4941323A | 1974-04-18 |
Attorney, Agent or Firm:
Masatake Shiga
Tadashi Takahashi
Sumio Tanai
Hiroshi Masui
Tadashi Takahashi
Sumio Tanai
Hiroshi Masui