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Title:
METHOD FOR PRODUCING MTW-TYPE ZEOLITE
Document Type and Number:
Japanese Patent JP2012153578
Kind Code:
A
Abstract:

To provide a method for producing an MTW-type zeolite without using a structure-directing agent and at low cost.

The method for producing an MTW-type zeolite includes reacting a reaction mixture containing a silica source, an alumina source, an alkali source and water with a zeolite seed crystal. As the reaction mixture, a reaction mixture is used having a composition in which when a zeolite is synthesized from the reaction mixture alone, the synthesized zeolite contains an MFI-type zeolite. As the seed crystal, a β-type zeolite is used in which the SiO2/Al2O3 ratio is 8-50 and which does not contain a structure-directing agent. The seed crystal is added to the reaction mixture in a ratio of 0.1-20 mass% with respect to the silica component in the reaction mixture, and the reaction mixture to which the seed crystal is added is sealed and heated at 100-200°C.


Inventors:
ITABASHI KEIJI
KAMIMURA YOSHIHIRO
OKUBO TATSUYA
Application Number:
JP2011014808A
Publication Date:
August 16, 2012
Filing Date:
January 27, 2011
Export Citation:
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Assignee:
NIPPON CHEMICAL IND
UNIV TOKYO
International Classes:
C01B39/46
Other References:
JPN6012054768; LOIHA, S. et al.: 'Synthesis of zeolite beta with pretreated rice husk silica and its transformation to ZSM-12' Mater. Chem. Phys. Vol. 115, 2009, p. 637-640
JPN6012054769; 上村佳大他: '種結晶添加法によるOSDA-free MTW型ゼオライトの合成とその特性' 第26回ゼオライト研究発表会 講演予稿集 , 2010, p. 19
Attorney, Agent or Firm:
Osamu Hatori
Yoshiyuki Matsushima