Title:
ニトロ化合物の製造法及び二酸化窒素の除去方法
Document Type and Number:
Japanese Patent JP4685996
Kind Code:
B2
Abstract:
In the invented process for producing a nitro compound, an organic substrate and nitrogen dioxide are reacted in the presence of oxygen or are reacted in a molar ratio of nitrogen dioxide to the organic substrate of less than 1 to yield a corresponding nitro compound. The reaction may be performed in the presence of N-hydroxyphthalimide or other imide compounds. Such organic substrates include (a) aliphatic hydrocarbons, (b) alicyclic hydrocarbons, (c) non-aromatic heterocyclic compounds each having a carbon atom on a ring, which carbon atom is bonded to a hydrogen atom, (d) compounds each having a carbon-hydrogen bond at the adjacent position to an aromatic ring, and (e) compounds each having a carbon-hydrogen bond at the adjacent position to a carbonyl group. This process can efficiently nitrate an organic substrate even under relatively mild conditions.
Inventors:
Yasutaka Ishii
Tatsuya Nakano
Tatsuya Nakano
Application Number:
JP13633999A
Publication Date:
May 18, 2011
Filing Date:
May 17, 1999
Export Citation:
Assignee:
Daicel Chemical Industry Co., Ltd.
International Classes:
B01D53/34; C07C201/06; B01D53/56; B01D53/77; C07B43/02; C07C201/08; C07C201/16; C07C203/08; C07C205/02; C07C205/04; C07C205/05; C07C205/06; C07C205/55
Domestic Patent References:
| JP52116427A | ||||
| JP4272720B2 | ||||
| JP9155152A |
Foreign References:
| EP0174600A1 |
Other References:
SUZUKI,H. et al,Iron(III)-catalyzed nitration of non-activated and moderately activated arenes with nitrogen dioxide-molecular oxygen under neutral conditions,Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry,1996年,No.19,p.2385-2389
Attorney, Agent or Firm:
Yukihisa Goto