Title:
マンガン触媒等を用いた有機化合物の製造法
Document Type and Number:
Japanese Patent JP4912557
Kind Code:
B2
Abstract:
A process of the present invention produces an organic compound by allowing a compound containing an electron attractive group of following Formula (1): wherein Y is an electron attractive group; and R and R are each a hydrogen atom or an organic group, where Y, R and R may respectively be combined with each other to form a ring with an adjacent carbon atom, to react with a compound containing an unsaturated carbon-carbon bond of following Formula (2) or (7): wherein R, R, R, R, R and R are each a hydrogen atom or an organic group, where R, R, R and R may respectively be combined to form a ring with one or two adjacent carbon atoms, and R and R may be combined to form a ring with adjacent two carbon atoms, in the presence of oxygen and a catalytic compound of a Group 5, 6, 7, 8 or 9 element of the Periodic Table of Elements to yield a compound of following Formula (3) or (8): wherein Z is a hydrogen atom or a hydroxyl group; and Y, R, R, R, R, R, R, R and R have the same meanings as defined above. This process can efficiently produce a compound having an alkyl group or alkenyl group bonded at the alpha position of an electron attractive group, or a derivative thereof, by catalytic radical addition reaction.
Inventors:
Yasutaka Ishii
Takahiro Iwahama
Sakaguchi Satoshi
Tatsuya Nakano
Takahiro Iwahama
Sakaguchi Satoshi
Tatsuya Nakano
Application Number:
JP2001565322A
Publication Date:
April 11, 2012
Filing Date:
March 08, 2001
Export Citation:
Assignee:
Daicel Corporation
International Classes:
C07C45/69; B01J31/04; B01J31/20; C07C45/33; C07C49/04; C07C49/395; C07C49/403; C07C49/413; C07C49/683; C07C49/82; C07C51/56; C07C67/347; C07C69/34; C07C69/708; C07C69/716; C07C253/30; C07C255/04; C07D307/20; C07D307/33; C07D307/77; C07D307/83; C07D313/04; C07B61/00
Domestic Patent References:
| JPS5452007A | 1979-04-24 | |||
| JPH09278675A | 1997-10-28 | |||
| JPH07247224A | 1995-09-26 |
Foreign References:
| US4322561A | 1982-03-30 | |||
| GB1134951A | 1968-11-27 |
Attorney, Agent or Firm:
Yukihisa Goto