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Patent Searching and Data


Title:
METHOD FOR PRODUCING OXIME
Document Type and Number:
Japanese Patent JP2012214441
Kind Code:
A
Abstract:

To provide an industrially advantageous production method in the production of an oxime by an ammoximation reaction of a ketone.

The method for producing an oxime includes a step (1) of oxidizing cumene to give cumene hydroperoxide, a step (2) of carrying out an ammoximation reaction of a ketone, cumene hydroperoxide obtained by the step (1) and ammonia in the presence of a catalyst to give a reaction mixture containing an oxime and 2-phenyl-2-propanol, a step (3) of recovering 2-phenyl-2-propanol having ≤4.0 wt.% of an oxime from the reaction mixture obtained by the step (2), a step (4) of hydrogenating 2-phenyl-2-propanol having ≤4.0 wt.% of an oxime obtained by the step (3) in the presence of a catalyst to give cumene and a step (5) of recycling at least a part of the cumene obtained by the step (4) to the step (1).


Inventors:
TSUJIUCHI SHO
FUKAO MASAMI
Application Number:
JP2012043085A
Publication Date:
November 08, 2012
Filing Date:
February 29, 2012
Export Citation:
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Assignee:
SUMITOMO CHEMICAL CO
International Classes:
C07C249/04; C07C251/44; C07B61/00; C07C1/20; C07C15/085
Attorney, Agent or Firm:
Toru Nakayama
Toru Sakamoto