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Title:
パラジウム含有担持触媒の製造方法
Document Type and Number:
Japanese Patent JP5001543
Kind Code:
B2
Abstract:
The present invention provides: a palladium-containing supported catalyst which is used for producing an α,β-unsaturated carboxylic acid from an olefin or an α,β-unsaturated aldehyde in high selectivity; a method for manufacturing the catalyst; and a method for producing an α,β-unsaturated carboxylic acid in high selectivity. In particular, the present invention resides in a method for manufacturing a palladium-containing supported catalyst for producing an α,β-unsaturated carboxylic acid from an olefin or an α,β-unsaturated aldehyde, comprising the step of reducing palladium oxide contained in a catalyst precursor wherein at least the palladium oxide is supported on a carrier. By using such a palladium-containing supported catalyst, an α,β-unsaturated carboxylic acid is produced through liquid-phase oxidation of an olefin or an α,β-unsaturated aldehyde with molecular oxygen.

Inventors:
Yoshino Himeno
Ninomiya
Ken Otaniuchi
Application Number:
JP2005292393A
Publication Date:
August 15, 2012
Filing Date:
October 05, 2005
Export Citation:
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Assignee:
Mitsubishi Rayon Co., Ltd.
International Classes:
B01J23/44; B01J37/08; B01J37/16; C07C27/12; C07C51/25; C07C57/045; C07B61/00; C07C45/35; C07C47/22
Domestic Patent References:
JP2002079087A
JP60139341A
JP2004519326A
JP2000202287A
JP51001389A
JP2004141863A
Foreign References:
WO2003068396A1
EP0145467A1
Other References:
久保俊彦ら,ゼオライトY上のパラジウムの分散状態と触媒活性,日本化学会誌(化学と工業化学),日本化学会,1974年 3月15日,Vol.1974, No.7,p.1199-1203
Attorney, Agent or Firm:
Akio Miyazaki
Ishibashi Masayuki
Shinichi Iwata
Masaaki Ogata