Title:
固相担持ルテニウム−ジアミン錯体及び光学活性化合物の製造方法
Document Type and Number:
Japanese Patent JP6689750
Kind Code:
B2
Abstract:
Provided is a solid-supported ruthenium complex represented by general formula (1), (2) or (3). Further provided are: a method for manufacturing a reduction product by reducing an organic compound in the presence of the solid-supported ruthenium complex and a hydrogen donor; a method for manufacturing an optically active alcohol, characterized by reducing a carbonyl group in a carbonyl compound in the presence of the solid-supported ruthenium complex and a hydrogen donor; and a method for manufacturing an optically active amine, characterized by reducing an imino group of an imine compound in the presence of the solid-supported ruthenium complex and a hydrogen donor.
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Inventors:
Taichiro Toge
Hideki Nara
Hideki Nara
Application Number:
JP2016553182A
Publication Date:
April 28, 2020
Filing Date:
October 13, 2015
Export Citation:
Assignee:
Takasago International Corporation
International Classes:
C07F15/00; B01J31/22; C07B53/00; C07B61/00; C07C29/159; C07C33/20; C07C33/22; C07C33/26; C07C41/26; C07C43/205; C07D215/06; C07D217/02; C07D307/42
Domestic Patent References:
JP2012067071A | ||||
JP2012520865A |
Foreign References:
WO2014068331A1 | ||||
WO2012153684A1 | ||||
WO2009132443A1 |
Other References:
Jonas Dimroth et al.,New Polymer-Supported Catalysts for the Asymmetric Transfer Hydrogenation of Acetophenone in Water -,Advanced Synthesis & Catalysis,2011年,353(8),1335-1344
Mizuki Tada et al.,Alternative Selective Oxidation Pathways for Aldehyde Oxidation and Alkene Epoxidation on a SiO2-Sup,Journal of the American Chemical Society,2010年,132(2),713-724
Mizuki Tada et al.,Photoinduced reversible structural transformation and selective oxidation catalysis of unsaturated r,Angewandte Chemie, International Edition,2008年,47(48),9252-9255
Mizuki Tada et al.,Selective formation of a coordinatively unsaturated metal complex at a surface: a SiO2-immobilized,,Angewandte Chemie, International Edition,2007年,46(38),7220-7223
Mizuki Tada et al.,Alternative Selective Oxidation Pathways for Aldehyde Oxidation and Alkene Epoxidation on a SiO2-Sup,Journal of the American Chemical Society,2010年,132(2),713-724
Mizuki Tada et al.,Photoinduced reversible structural transformation and selective oxidation catalysis of unsaturated r,Angewandte Chemie, International Edition,2008年,47(48),9252-9255
Mizuki Tada et al.,Selective formation of a coordinatively unsaturated metal complex at a surface: a SiO2-immobilized,,Angewandte Chemie, International Edition,2007年,46(38),7220-7223
Attorney, Agent or Firm:
Shinichiro Tanaka
Disciple Maru Ken
Atsushi Hakoda
Kenji Asai
Kazuo Yamazaki
Satsuki Ichikawa
Hironobu Hattori
Kobayashi Machiko
Disciple Maru Ken
Atsushi Hakoda
Kenji Asai
Kazuo Yamazaki
Satsuki Ichikawa
Hironobu Hattori
Kobayashi Machiko