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Title:
固相担持ルテニウム−ジアミン錯体及び光学活性化合物の製造方法
Document Type and Number:
Japanese Patent JP6689750
Kind Code:
B2
Abstract:
Provided is a solid-supported ruthenium complex represented by general formula (1), (2) or (3). Further provided are: a method for manufacturing a reduction product by reducing an organic compound in the presence of the solid-supported ruthenium complex and a hydrogen donor; a method for manufacturing an optically active alcohol, characterized by reducing a carbonyl group in a carbonyl compound in the presence of the solid-supported ruthenium complex and a hydrogen donor; and a method for manufacturing an optically active amine, characterized by reducing an imino group of an imine compound in the presence of the solid-supported ruthenium complex and a hydrogen donor.

Inventors:
Taichiro Toge
Hideki Nara
Application Number:
JP2016553182A
Publication Date:
April 28, 2020
Filing Date:
October 13, 2015
Export Citation:
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Assignee:
Takasago International Corporation
International Classes:
C07F15/00; B01J31/22; C07B53/00; C07B61/00; C07C29/159; C07C33/20; C07C33/22; C07C33/26; C07C41/26; C07C43/205; C07D215/06; C07D217/02; C07D307/42
Domestic Patent References:
JP2012067071A
JP2012520865A
Foreign References:
WO2014068331A1
WO2012153684A1
WO2009132443A1
Other References:
Jonas Dimroth et al.,New Polymer-Supported Catalysts for the Asymmetric Transfer Hydrogenation of Acetophenone in Water -,Advanced Synthesis & Catalysis,2011年,353(8),1335-1344
Mizuki Tada et al.,Alternative Selective Oxidation Pathways for Aldehyde Oxidation and Alkene Epoxidation on a SiO2-Sup,Journal of the American Chemical Society,2010年,132(2),713-724
Mizuki Tada et al.,Photoinduced reversible structural transformation and selective oxidation catalysis of unsaturated r,Angewandte Chemie, International Edition,2008年,47(48),9252-9255
Mizuki Tada et al.,Selective formation of a coordinatively unsaturated metal complex at a surface: a SiO2-immobilized,,Angewandte Chemie, International Edition,2007年,46(38),7220-7223
Attorney, Agent or Firm:
Shinichiro Tanaka
Disciple Maru Ken
Atsushi Hakoda
Kenji Asai
Kazuo Yamazaki
Satsuki Ichikawa
Hironobu Hattori
Kobayashi Machiko