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Title:
遷移金属触媒及びα-オレフィン及びビニル化合物重合体の製造方法
Document Type and Number:
Japanese Patent JP4819270
Kind Code:
B2
Abstract:
A catalyst comprising (a) a complex of Group 8 to 10 transition metal of the Periodic Table, (b) clay, clay mineral or a ion-exchangeable layered compound, and (c) an amine compound or its adduct with Br phi nsted acid; a catalyst comprising (a) a chelate complex of Group 4 to 6 transition metal of the Periodic Table or a complex of Group 8 to 10 transition metal of the Periodic Table, (b) clay, clay mineral or a ion-exchangeable layered compound, and (c) a quaternary ammonium salt; and a catalyst comprising (a) a complex of Group 4 to 6 transition metal of the Periodic Table or a complex of Group 8 to 10 transition metal of the Periodic Table and a co-catalyst component produced by contacting (b) clay, clay mineral or a ion-exchangeable layered compound, (c) an amine compound, its adduct with Br phi nsted acid or a quaternary ammonium salt, and (d) an organosilane compound. Since these catalysts show high oligomerization activity of ethylene, alpha -olefins can be efficiently produced with low costs from ethylene. By using the catalysts, vinyl-terminated, linear alpha -olefins (oligomers) having a molecular weight of 10000 or less or polyolefins having a molecular weight exceeding 10000 can be also produced efficiently with low costs.

Inventors:
Haruhito Sato
Kuramoto Masahiko
Masami Watanabe
Application Number:
JP2001523130A
Publication Date:
November 24, 2011
Filing Date:
September 14, 2000
Export Citation:
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Assignee:
IDEMITSU KOSAN CO.,LTD.
International Classes:
B01J31/22; C07C2/08; C07C2/32; C08F4/62; C08F4/64; C08F4/70; C08F10/00; C08F12/04; C08F4/659; C08F4/6592; C08F110/02
Domestic Patent References:
JPH10231312A1998-09-02
JPH11140111A1999-05-25
JPH11335408A1999-12-07
JPH06263427A1994-09-20
JPS59216631A1984-12-06
JP2000169515A2000-06-20
JP2000271484A2000-10-03
JPH10231312A1998-09-02
JPH11140111A1999-05-25
JPH11335408A1999-12-07
JPH06263427A1994-09-20
JPS59216631A1984-12-06
JP2000169515A2000-06-20
JP2000271484A2000-10-03
Foreign References:
WO1999048930A11999-09-30
WO1999014247A11999-03-25
WO1999048930A11999-09-30
WO1999014247A11999-03-25
Attorney, Agent or Firm:
Tamotsu Otani