PURPOSE: To recover effectively uranium excellent in the purity by dissolving the nucleus fuel scrap contg. Gd2O3 in a mineral acid to solvent-extract uranium, washing an organic phase contg. uranium and thereafter back-extracting it with an aqueous system.
CONSTITUTION: The nucleus fuel scrap contg. Gd2O3 is dissolved in a mineral acid such as nitric acid added with NaNO3. A solvent such as tributylphosphate is added to this soln. to solvent-extract uranium. The organic phase contg. utanium is washed with water or dilute nitric acid to transfer Gd content or the like to an aqueous phase. In this washing, the volume ratio of aqueous phase/organic phase is regulated to ≤1/10. Uranium is back-extracted from the washed organic phase by using water or dilute mineral acid. In this way, uranium can be recovered in the excellent purity.
YAMA TERUYOSHI
MIYAJIMA YOSHIKI
JPS59141426A | 1984-08-14 | |||
JPS5924732A | 1984-02-08 |
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