Title:
METHOD FOR SYNTHESIZING COMPOUND BY SONOGASHIRA-HAGIHARA REACTION USING PALLADIUM NANOPARTICLE AS CATALYST
Document Type and Number:
Japanese Patent JP2013227305
Kind Code:
A
Abstract:
To provide a synthetic method with which a compound is efficiently synthesized, while there is no problem associated with current homogeneous and heterogeneous palladium catalysts and activity of palladium is effectively exhibited, in a chemical synthetic reaction using a palladium catalyst, particularly in a Sonogashira-Hagihara reaction.
In a synthetic method of a compound, a Sonogashira-Hagihara reaction is carried out in the presence of palladium nanoparticles prepared by dispersing a heterogeneous palladium catalyst in an alkaline solution and subjecting the heterogeneous palladium catalyst to alkali processing.
Inventors:
FUJISAWA NAOTAKE
Application Number:
JP2013068804A
Publication Date:
November 07, 2013
Filing Date:
March 28, 2013
Export Citation:
Assignee:
HOKKO CHEM IND CO
International Classes:
C07C2/86; B01J23/89; C07C15/54; C07C17/32; C07C25/24; C07C41/30; C07C43/215; C07C45/67; C07C47/548; C07C67/293; C07C69/017; C07C201/12; C07C205/06; C07C209/74; C07C211/45; C07C253/30; C07C255/50; C07B61/00
Domestic Patent References:
| JP2004298802A | 2004-10-28 | |||
| JP2005254092A | 2005-09-22 | |||
| JP2010070753A | 2010-04-02 |
Other References:
TAMAMI, BAHMAN; ALLAHYARI, HAMED; FARJADIAN, FATEMEH; GHASEMI, SOHEILA: "Synthesis and applications of poly(N-vinylimidazole) grafted silica-containing palladium nanoparticl", IRANIAN POLYMER JOURNAL, vol. (2011), 20(9), 699-712, JPN7016002741, 2011, ISSN: 0003475401
DUTTA, PIYALI; SARKAR, AMITABHA: "Palladium Nanoparticles Immobilized on Chemically Modified Silica Gel: Efficient Heterogeneous Catal", ADVANCED SYNTHESIS & CATALYSIS, vol. (2011), 353(14-15), 2814-2822, JPN7016002742, 2011, ISSN: 0003475402
KHALAFI-NEZHAD, ALI; PANAHI, FARHAD: "Immobilized palladium nanoparticles on a silica-starch substrate (PNP-SSS): as an efficient heteroge", GREEN CHEMISTRY, vol. (2011), 13(9), 2408-2415, JPN7016002743, 2011, ISSN: 0003475403
DUTTA, PIYALI; SARKAR, AMITABHA: "Palladium Nanoparticles Immobilized on Chemically Modified Silica Gel: Efficient Heterogeneous Catal", ADVANCED SYNTHESIS & CATALYSIS, vol. (2011), 353(14-15), 2814-2822, JPN7016002742, 2011, ISSN: 0003475402
KHALAFI-NEZHAD, ALI; PANAHI, FARHAD: "Immobilized palladium nanoparticles on a silica-starch substrate (PNP-SSS): as an efficient heteroge", GREEN CHEMISTRY, vol. (2011), 13(9), 2408-2415, JPN7016002743, 2011, ISSN: 0003475403
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