Title:
高分子錯体結晶の合成方法
Document Type and Number:
Japanese Patent JP5297593
Kind Code:
B2
Abstract:
Disclosed is a synthesis method for synthesizing in a short time and selectively a microcrystal of a polymer complex having three three-dimensionally and regularly arranged channels. Specifically disclosed is a synthesis method of a polymer complex crystal wherein (1) a metallic solution, which is a mixture of zinc halide(II) and a solvent A that can dissolve the zinc halide, is mixed with (2) a ligand solution, which is a mixture of a tridentate ligand that has three coordination sites coordinated to zinc of the zinc halide and a solvent B that can dissolve the tridentate ligand, to be a single-phase solution, thereby synthesizing a microcrystal of a polymer complex having a three-dimensional coordination network formed by coordinating the tridentate ligand to the zinc and having channels that are three-dimensionally and regularly arranged in the three-dimensional coordination network.
Inventors:
Makoto Fujita
Kono
Go Haneda
Kiyooki Nakanishi
Takahiro Kojima
Kono
Go Haneda
Kiyooki Nakanishi
Takahiro Kojima
Application Number:
JP2007057611A
Publication Date:
September 25, 2013
Filing Date:
March 07, 2007
Export Citation:
Assignee:
National University Corporation Tokyo University
TOYOTA JIDOSHA KABUSHIKI KAISHA
TOYOTA JIDOSHA KABUSHIKI KAISHA
International Classes:
C08G79/00; C07D401/14
Domestic Patent References:
| JP2002126512A | ||||
| JP2006188560A |
Attorney, Agent or Firm:
Kishimoto Tatsuto
Akihiko Yamashita
Akihiko Yamashita