To control Mooney viscosity while a siloxane-functionalized polymer ages.
A method for controlling any increase in Mooney viscosity during aging of the siloxane-functionalized polymer includes the step of adding, after polymerization but still in the presence of an inert solvent and prior to contacting the polymer with water, a viscosity stabilizing effective amount of a viscosity stabilizing agent selected from the group consisting of alkyl alkoxysilanes of structural formula R1nSi(OR2)4-n (wherein R1 is selected from the group consisting of C1 to C20 alkyl, C4 to C10 cycloalkyl, or C5 to C20 aromatic groups, wherein R2 may be the same as or different from R1 and is selected from the group consisting of C1 to C20 alkyl, C4 to C10 cycloalkyl, or C5 to C20 aromatic groups, and n is an integer from 1 to 3). The method provides for the stabilization of Mooney viscosity of siloxane-functionalized polymers at any given level upon aging.
LIN CHEN-CHY
HERGENROTHER WILLIAM L
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