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Title:
MODIFYING METHOD OF PROPYLENE-ETHYLENE BLOCK COPOLYMER
Document Type and Number:
Japanese Patent JPS5876444
Kind Code:
A
Abstract:

PURPOSE: To obtain a copolymer having improved moldability, impact resistance and elongation at break and high rigidity, by melt kneading a specific amount of an organic peroxide with a specific propylene-ethylene block copolymer.

CONSTITUTION: 10ppm or more and less than 50ppm organic peroxide is melt kneaded with (c) a block copolymer, obtained by polymerizing ethylene and then the ethylene and propylene in two stages in the presence of the same catalyst, and consisting of (a) 80W92wt% propylene homopolymer or propylene- ethylene random copolymer with ≤10wt% ethylenic content and (b) 8W20wt% propylene-ethylene random copolymer with 35W60wt% ethylenic content, at 180W250°C for 10sec or longer and within 5min. Preferably, (d) the resultant treated composition has 20W200%, preferably 40W75%, MFI improvement ratio defined by formulaI. The copolymer to be treated has 1.3W7MFI ratio defined by formula II from the standpoint of the impact resistance and appearance of molded articles.


Inventors:
HASUO MASAYOSHI
SUGA SADANORI
KOJIMA KAZUHISA
SUZUKI YUKITOSHI
KUMAZAKI SHIYOUJI
Application Number:
JP17434781A
Publication Date:
May 09, 1983
Filing Date:
October 30, 1981
Export Citation:
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Assignee:
MITSUBISHI CHEM IND
International Classes:
C08L51/00; C08F8/50; C08K5/14; C08L23/00; C08L51/02; C08L53/00; C08L77/00; C08L101/00; (IPC1-7): C08K5/14; C08L53/00
Domestic Patent References:
JPS4821731A
JPS5379988A1978-07-14
Attorney, Agent or Firm:
Hajime Hasegawa