Title:
一置換（フルオロアルキル）エチレン類及びその製造方法
Document Type and Number:
Japanese Patent JP6578116
Kind Code:
B2
Abstract:
PROBLEM TO BE SOLVED: To provide a method of efficiently producing monosubstituted(fluoroalkyl)ethylenes.SOLUTION: The method comprises reacting a 1-chloro-2-(fluoroalkyl)ethylene with an organoboron compound under coexistence of an alkylphosphine coordinated palladium catalyst, an alkali metal salt and water so as to obtain a monosubstituted(fluoroalkyl)ethylene represented by the general formula (5). (In the formula, R represents a naphthalene-1-yl group or the like, and Rrepresents C1-4 fluoroalkyl group.)SELECTED DRAWING: None
Inventors:
Yamakawa Satoshi
Tetsuya Yamamoto
Tetsuya Yamamoto
Application Number:
JP2015062367A
Publication Date:
September 18, 2019
Filing Date:
March 25, 2015
Export Citation:
Assignee:
Sagami Central Chemical Research Institute
Tosoh Finechem Co., Ltd.
Tosoh Finechem Co., Ltd.
International Classes:
C07B37/04; C07C1/32; C07C15/58; C07C17/263; C07C21/19; C07C22/08; C07C25/13; C07C29/32; C07C33/48; C07C41/30; C07C43/225; C07C45/68; C07C47/575; C07C49/76; C07C49/813; C07C67/343; C07C69/76; C07C201/12; C07C205/11; C07C209/68; C07C211/54; C07C231/12; C07C233/65; C07C253/30; C07C255/50; C07C269/06; C07C271/28; C07C315/04; C07C317/14; C07C319/20; C07C321/28; C07D207/33; C07D213/64; C07D215/12; C07D239/34; C07D307/79; C07D333/12; C07F7/12; C07F7/18
Domestic Patent References:
| JP2010533726A | ||||
| JP2013505935A |
Other References:
EGAMI, H. et al.,Journal of Fluorine Chemistry,2014年,167,172-178
DATABESE REGISTRY [ONLINE] Retrieved from STN,2004年 2月19日,検索日:2018年11月1日,CAS登録番号:651724-52-6
CHEN, C. et al.,Tetrahedron Letters,1999年,40,827-830
CLAPHAM, K. M. et al.,Journal of Organic Chemistry,2008年,73,2176-2181
ITOH, T. et al.,Tetrahedron Letters,2005年,46,3573-3577
YAMAMOTO, T. et al.,Organic Letters,2012年,Vol.14, No.13,pp.3454-3457
LEMAY, A. B. et al.,Journal of Organic Chemistry,2006年,71,3615-3618
JENNINGS, M. P. et al.,Journal of Organic Chemistry,2000年,65,8763-8766
LIRON, F. et al.,Journal of Organic Chemistry,2007年,72,2220-2223
DATABESE REGISTRY [ONLINE] Retrieved from STN,2004年 2月19日,検索日:2018年11月1日,CAS登録番号:651724-52-6
CHEN, C. et al.,Tetrahedron Letters,1999年,40,827-830
CLAPHAM, K. M. et al.,Journal of Organic Chemistry,2008年,73,2176-2181
ITOH, T. et al.,Tetrahedron Letters,2005年,46,3573-3577
YAMAMOTO, T. et al.,Organic Letters,2012年,Vol.14, No.13,pp.3454-3457
LEMAY, A. B. et al.,Journal of Organic Chemistry,2006年,71,3615-3618
JENNINGS, M. P. et al.,Journal of Organic Chemistry,2000年,65,8763-8766
LIRON, F. et al.,Journal of Organic Chemistry,2007年,72,2220-2223