To obtain a multilayer structure having excellent oxygen barrier properties and odor barrier properties as well as excellent transparency.

The multilayer structure comprises a multilayer sheet having a layer obtained by adding an inorganic filler (B) having an aspect ratio of 5 or more such as a talc or the like and adding a deodorant (F) such as a zeolite or the like to a barrier resin (A) such as an ethylene/vinyl alcohol copolymer or the like and a layer obtained by adding the inorganic filler (B) and the deodorant (F) to a thermoplastic resin except the barrier resin (A) such as a polyamide or the like and manufactured by co-extrusion and at least uniaxially stretching by a stretching ratio of 2 or more.