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Title:
NEW BENZIMIDAZOLOCARBOCYANINE DERIVATIVE, SILVER HALIDE EMULSION CONTAINING THE SAME, SILVER HALIDE-BASED PHOTOGRAPHIC PHOTOSENSITIVE MATERIAL AND SILVER HALIDE-BASED COLOR PHOTOGRAPHIC PHOTOSENSITIVE MATERIAL
Document Type and Number:
Japanese Patent JPH11222482
Kind Code:
A
Abstract:

To obtain a new compound excellent in the color sensitization in green color short wave region and useful as a photosensitive coloring matter subject to spectral sensitization in high sensitivity without deteriorating the storage stability of silver halide emulsions.

This new compoind is shown by formula I (R1 to R4 are each an aliphatic group; V1 to V4 are each H or the like; X is an ion necessary of neutralizing intermolecular electric charge; (n) is a number necessary for neutralizing intermolecular electric charge; with a proviso that at least one of R1 to R4 is a group of the formula L-Q, at least one of the others being a sulfoalkyl; L is an alkylene which may be interposed with a chalcogen; Q is a heterocycle), e.g. a compound of formula II. The compound of formula I can be synthesized based on a conventionally known method; for example, for the compound of formula II, it is obtained by reaction between a compound of formula III and a compound of formula IV in dimethyl sulfoxide in the presence of 1,8-diazabicyclo [5,4,0] undec-7-ene.


Inventors:
TANAKA TATSUO
FUKUSAKA KIYOSHI
KAGAWA NOBUAKI
Application Number:
JP2203698A
Publication Date:
August 17, 1999
Filing Date:
February 03, 1998
Export Citation:
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Assignee:
KONISHIROKU PHOTO IND
International Classes:
G03C1/18; C07D235/20; C07D401/06; C07D401/14; C07D403/14; C07D405/06; C07D405/14; C07D409/14; C07D413/14; C07D417/06; C07D417/14; C09B23/00; (IPC1-7): C07D235/20; C07D401/06; C07D401/14; C07D403/14; C07D405/06; C07D405/14; C07D409/14; C07D413/14; C07D417/06; C07D417/14; C09B23/00; G03C1/18