Title:
NEW BISMUTH COMPOUND AND METHOD FOR SELECTIVELY OXIDIZING ALCOHOL USING THE COMPOUND
Document Type and Number:
Japanese Patent JP2005023052
Kind Code:
A
Abstract:
To provide a method for selectively oxidizing alcohols into aldehydes or ketones under a mild condition which is required in an organic synthesis field or the other fields, particularly for oxidizing a hardly reacting 2,2,2-trifluoro-1-substituted ethanol in a short time in a high yield.
This method for selectively oxidizing alcohols is characterized by using, as an oxidizing agent, tris(p-substituted phenyl)bismuth dichlorides or tris(o,p-substituted phenyl)bismuth dichlorides having an electron-withdrawing group at least at para-position of a phenyl group.
Inventors:
MATANO YOSHIHIRO
YAMADA HISATSUGU
NOMURA DAN
IMAHORI HIROSHI
YAMADA HISATSUGU
NOMURA DAN
IMAHORI HIROSHI
Application Number:
JP2003270582A
Publication Date:
January 27, 2005
Filing Date:
July 03, 2003
Export Citation:
Assignee:
TOKYO KASEI KOGYO KK
International Classes:
C07C45/29; C07B61/00; C07C47/21; C07C49/80; C07F9/94; (IPC1-7): C07F9/94; C07C45/29; C07C47/21; C07C49/80