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Patent Searching and Data


Title:
NEW INTERMEDIATE
Document Type and Number:
Japanese Patent JPH10226656
Kind Code:
A
Abstract:

To obtain a new compound useful as an intermediate for producing a fluorescent whitening agent.

This compound is shown by formula I (R is H or a 1-4C alkyl; Y is H, a 1-4C alkyl, a 1-4C alkoxy, etc.) such as 4-vinyl-4'-α-hydroxyethyl- biphenyl. The compound of formula I is obtained, for example, by partially dehydrating a compound of formula II (Y is H, etc.) in a high-boiling solvent (e.g. a polyalkylene glycol such as polyethylene glycol) or by using a solvent (triethylene glycol dimethyl ether) not containing an acid at 180-220°C under normal pressure in the presence of an effective amount of a styrene monomer polymerization inhibitor (quinone, tert-butylpyrocatechol, etc.) (in the case of using the solvent not containing an acid, a small amount of an acidic compound such as p-toluenesulfonic acid exists) and the reaction is stopped immediately after detection of the optimum amount of the compound of formula II.


Inventors:
SIEBENHAAR BERND
CASAGRANDE BRUNO
ELIU VICTOR
Application Number:
JP34988697A
Publication Date:
August 25, 1998
Filing Date:
December 19, 1997
Export Citation:
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Assignee:
CIBA GEIGY AG
International Classes:
B01J23/44; B01J31/22; C07B61/00; C07C1/24; C07C15/50; C07C17/35; C07C25/24; C07C29/60; C07C33/28; C07C33/48; C07C41/18; C07C43/205; C07C43/23; C07C303/22; C07C303/32; C07C309/32; C07C309/42; (IPC1-7): C07C15/50; B01J23/44; B01J31/22; C07C1/24; C07C17/35; C07C25/24; C07C29/60; C07C33/28; C07C33/48; C07C41/18; C07C43/205; C07C43/23; C07C303/22; C07C303/32; C07C309/32; C07C309/42
Attorney, Agent or Firm:
Masao Okabe (11 others)