Title:
NOVEL SUBSTANCE, METHOD FOR PRODUCING HEXANUCLEAR COPPER COMPLEX, METHOD FOR PRODUCING DINUCLEAR COPPER COMPLEX, AND METHOD FOR OXIDIZING METHANE TO METHANOL
Document Type and Number:
Japanese Patent JP2023043488
Kind Code:
A
Abstract:
To provide an oxidation catalyst which is a novel substance that can directly oxidize gaseous alkane such as methane more efficiently and convert it to alcohol.SOLUTION: A novel substance hexanuclear copper complex [Cu6(μ3-OH)2(μ-OH)4(6-hpaC0)2](ClO4)6 is used as an oxidation catalyst. The hexanuclear copper complex [Cu6(μ3-OH)2(μ-OH)4(6-hpaC0)2](ClO4)6 is produced by performing nitrogen substitution reaction in which 3 equivalents of copper perchlorate is added to 6,6'-bis[[bis(2-pyridylmethyl)amino]methyl]-2,2'-bipyridine (6-hpaC0 ligand). The oxidation catalyst can also be used for cyclohexane oxidation or the like other than methane.SELECTED DRAWING: Figure 1
Inventors:
KODERA MASATO
TANAKA KOSEI
TANAKA KOSEI
Application Number:
JP2021151154A
Publication Date:
March 29, 2023
Filing Date:
September 16, 2021
Export Citation:
Assignee:
DOSHISHA
International Classes:
C07F1/08; B01J31/22; C07C29/48; C07C31/04; C07C33/14
Attorney, Agent or Firm:
Patent Attorney Corporation Maeda Patent Office
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